Journal :   Asian Journal of Research in Chemistry

Volume No. :   3

Issue No. :  1

Year :  2010

Pages :   214-219

ISSN Print :  0974-4169

ISSN Online :  0974-4150


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Nickel(II) Selective Poly(Vinyl Chloride) Membrane Electrode Based on Novel Macrocyclic Compound 11,14-Diaza-4,7-Dioxo-2(3),8(9)-Dibenzoyl-Cyclotetradeca-10,14(1)-Diene as Neutral Carrier



Address:   Susheel Kumar Sindhu1*, Sunil Kumar1,2 and LR Singh2
1Department of Chemistry, S.S.V. Post Graduate College, Hapur, India
2Department of Chemistry, B.S.A. College, Mathura (U.P.) India
*Corresponding Author
DOI No:

ABSTRACT:
A PVC membrane based nickel(II) selective electrode was constructed using 11,14-diaza-4,7-dioxo-2(3),8(9)-dibenzoyl-cyclotetradeca-10,14(1)-diene (DADOCTD) as a neutral carrier. The sensor exhibits a Nernstian response for Ni(II) ions over a wide concentration range of 3.9 x 10-6 - 1.0 x 10-1 with a slope of 29.0 mV/decade. It has a relatively fast response time and can be used for 120 days without any considerable divergence in potentials. The proposed sensor revealed relatively good selectively and high sensitivity for Ni(II) over a bi-, tri- and tetravalent metal ions and could be used in a pH range of 3-8. It was successfully also used as an indicator electrode in potentiometer titration and in analysis of concentration of nickel in real samples.
KEYWORDS:
Nickel(II) Selective Poly(Vinyl Chloride) Membrane Electrode Based on Novel Macrocyclic Compound 11,14-Diaza-4,7-Dioxo-2(3),8(9)-Dibenzoyl-Cyclotetradeca-10,14(1)-Diene as Neutral Carrier.
Cite:
Susheel Kumar Sindhu, Sunil Kumar, LR Singh. Nickel(II) Selective Poly(Vinyl Chloride) Membrane Electrode Based on Novel Macrocyclic Compound 11,14-Diaza-4,7-Dioxo-2(3),8(9)-Dibenzoyl-Cyclotetradeca-10,14(1)-Diene as Neutral Carrier. Asian J. Research Chem. 3(1): Jan.-Mar. 2010; Page 214-219.
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