Journal :   Asian Journal of Research in Chemistry

Volume No. :   4

Issue No. :  1

Year :  2011

Pages :   95-99

ISSN Print :  0974-4169

ISSN Online :  0974-4150


Registration

Allready Registrered
Click to Login

New and Efficient Route for the Synthesis of Ketone from Alkyl Halide Using α-Chloro Nitrone as Oxidizing Reagent



Address:   Bhaskar Chakraborty* and Prawin K. Sharma
Organic Chemistry laboratory, Sikkim Government College, Gangtok, Sikkim 737102, India
*Corresponding Author
DOI No:

ABSTRACT:
Consecutive SN2 reaction of a-chloro nitrones are studied with isopropyl halides and the nitrones are found to have remarkable oxidizing properties for the conversion of isopropyl halides to ketones with high yields. In addition, the side product obtained can serve as efficient dipolarophile in 1,3-Dipolar cycloaddition reaction to produce spiro cycloadduct in good yield.
KEYWORDS:
α-chloro nitrone, ketone synthesis, reusable side product.
Cite:
Bhaskar Chakraborty, Prawin K. Sharma. New and Efficient Route for the Synthesis of Ketone from Alkyl Halide Using α-Chloro Nitrone as Oxidizing Reagent. Asian J. Research Chem. 4(1): January 2011; Page 95-99.
[View HTML]      [View PDF]



Visitor's No. :   126945