Journal :   Asian Journal of Research in Chemistry

Volume No. :   4

Issue No. :  11

Year :  2011

Pages :   1765-1768

ISSN Print :  0974-4169

ISSN Online :  0974-4150


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Synthesis, Characterization, Metal Ion Intake and Antibacterial Activity of Schiff Base Complexes of Zr(IV) and Th(IV) Derived From Di-α-Formyl Methoxybis (3-Pentadecenylphenyl) Methane [DFMPM] and Ethylenediamine



Address:   C. Isac Sobana Raj1*, M. Christudhas2 and G. Allen Gnana Raj3
1Research Scholar, Department of Chemistry and Research Centre, Scott Christian College (Autonomous), Nagercoil – 629003, India.
2Department of Chemistry, N.M. Christian College, Marthandam -629165, India.
3Dept. of Chemistry and Research Centre, Scott Christian College (Autonomous), Nagercoil- 629003, India.
*Corresponding Author
DOI No:

ABSTRACT:
The Zr(IV) and Th(IV)-di-a-formylmethoxy bis(3-pentadecenylphenyl)methane (DFMPM) ethylediamine complex were synthesized and characterized by elemental analysis, conductivity measurements, electronic, infrared, 1HNMR spectral measurements, metal ion intake and antibacterial studies. The conductance measurements indicate that all the complexes are non-electrolytes. The infrared spectra indicate the coordination of imino nitrogen, M-N and M-O bonds. UV-visible spectra could not provide structural details of these complexes. 1HNMR data are consistent with IR spectral data. The results indicate that both Zr(IV) and Th(IV) ions are octacoordinated and have moderate antibacterial activity. The metal ion intake indicates the ligand can be used for the extraction of these metals from water.
KEYWORDS:
Cardanol, Formaldehyde, Epichlorohydrin, Ethylendiamine Schiff base.
Cite:
C. Isac Sobana Raj, M. Christudhas, G. Allen Gnana Raj. Synthesis, Characterization, Metal Ion Intake and Antibacterial Activity of Schiff Base Complexes of Zr(IV) and Th(IV) Derived From Di-α-Formyl Methoxybis (3-Pentadecenylphenyl) Methane [DFMPM] and Ethylenediamine. Asian J. Research Chem. 4(11): Nov., 2011; Page 1765-1768.
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