Journal :   Asian Journal of Research in Chemistry

Volume No. :   4

Issue No. :  12

Year :  2011

Pages :   1861-1863

ISSN Print :  0974-4169

ISSN Online :  0974-4150


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Kinetics of Oxidation of 2-Hydroxy-1-Naphthalidene Anil and Substituted Anils by Ce4+  Ce3+ Redox System in Aqueous Sulphuric Acid Medium



Address:   Sharad Sankhe1, Ramesh Yamgar1 and Umesh N. Pol2
1Chemistry Research Laboratory, Patkar College, Goregaon (W), Mumbai 400 062.
2Department of Chemistry Willingdon College, Sangli, Maharashtra.
*Corresponding Author
DOI No:

ABSTRACT:
The kinetics of oxidation of the Schiff base 2-hydroxy - 1 - Naphthalidene anil and substituted anils such as 2’ – methoxy - 2 - hydroxy - 1 - naphthalidene anil, 3’ – Methoxy - 2 - Hydroxy - 1 - Naphthalidene anil and 4’ – Methoxy - 2 - Hydroxy - 1- Naphthalidene anil by Ce (IV) as oxidant in aqueous sulphuric acid medium. The kinetic study is carried out by using various concentrations of oxidants and the substrates, which is found to be the first order reaction. A suitable plaussible mechanism has been suggested on the basis of kinetic results.
KEYWORDS:
Kinetics of oxidation, Schiff Base, Redox system, Reaction Mechanism.
Cite:
Sharad Sankhe, Ramesh Yamgar, Umesh N. Pol. Kinetics of Oxidation of 2-Hydroxy-1-Naphthalidene Anil and Substituted Anils by Ce4+  Ce3+ Redox System in Aqueous Sulphuric Acid Medium. Asian J. Research Chem. 4(12): Dec., 2011; Page 1861-1863.
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