Journal :   Asian Journal of Research in Chemistry

Volume No. :   5

Issue No. :  10

Year :  2012

Pages :   1238-1241

ISSN Print :  0974-4169

ISSN Online :  0974-4150


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Synthesis and Thermokinetic Studies of Co(II), Ni(II), Cu(II), Cr(III), Mn(III), Fe(III), VO(IV), Zr(IV) and UO2(VI) Complexes Derived from Bidentate Thiazole Schiff Base



Address:   S. R. Kelode1* and P. R. Mandlik2
1Department of Engg. Chemistry, Jagadambha College of Engineering and Tech. Yavatmal
2P. G. Department of Chemistry, Shri Shivaji Science College, Amravati
*Corresponding Author
DOI No:

ABSTRACT:
The new thiazole Schiff base have been synthesized by condensing 2-hydroxy-5-chloro acetophenone and 4-(p-hydroxyphenyl)-2-aminothiazole. The metal complexes were obtained as a result of interaction of Schiff base ligand and metal ions Co(II), Ni(II), Cu (II), Cr (III), Mn(III), Fe (III), VO (IV), Zr (IV) and UO2 (VI). The complexes have been characterized on the basis of elemental analysis, infrared, molar conductance, magnetic Susceptibilities, and theromogravimetric analysis. The kinetic analysis of the thermogravimetric data was performed by using Broido, Horowitz-Metzger and Freeman-Carroll method, which confirm first order kinetics and kinetic compensation effect.
KEYWORDS:
Thiazole Schiff Base, Molar conductance, Thermal.
Cite:
S. R. Kelode, P. R. Mandlik. Synthesis and Thermokinetic Studies of Co(II), Ni(II), Cu(II), Cr(III), Mn(III), Fe(III), VO(IV), Zr(IV) and UO2(VI) Complexes Derived from Bidentate Thiazole Schiff Base. Asian J. Research Chem. 5(10): October, 2012; Page 1238-1241.
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