Journal :   Asian Journal of Research in Chemistry

Volume No. :   5

Issue No. :  2

Year :  2012

Pages :   191-192

ISSN Print :  0974-4169

ISSN Online :  0974-4150


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Oxidative Degradtion and Associated Complexation of Ethylacetoacetate by Cr (VI) Based Oxidant



Address:   K. Akhtar1, R. Ranjan1* and M. Alam2
1PG Department of Chemistry, Ranchi College, Ranchi-834008
2University Department of Chemistry, Ranchi University, Ranchi-834008
*Corresponding Author
DOI No:

ABSTRACT:
The present paper investigates the action of di-tertiary butyl chromate (TBC) - a Cr(VI) based oxidant - on ethylacetoacetate with following aims: (a) Whether degradation occurs along with oxidation? (b) Whether Cr in reduced state enters into complexation with the oxidised fragments or with the unreacted substrate itself? (c) Whether the oxidation is selective i.e., does arresting the reaction at different stages (by taking different substrate: TBC molar ratios) result into same product or not.
KEYWORDS:
TBC, TBA, FTIR, TLC, TG, DTA.
Cite:
K. Akhtar, R. Ranjan, M. Alam. Oxidative Degradtion and Associated Complexation of Ethylacetoacetate by Cr (VI) Based Oxidant. Asian J. Research Chem. 5(2): February 2012; Page 191-192.
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