Journal :   Asian Journal of Research in Chemistry

Volume No. :   5

Issue No. :  6

Year :  2012

Pages :   779-780

ISSN Print :  0974-4169

ISSN Online :  0974-4150


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Synthesis and Characterization of Novel Schiff Base Complexes of Some First Row Transition Metal Ions.



Address:   A.K. Ibrahim Sheriff2, S. Syed Shafi1, G. Sasi Kumar2, T.N. Balaji2
1Dept. of Chemistry, Thiruvalluvar University, Serkadu, Vellore-632 106, India.
2PG & Research Dept. of Chemistry, C. Abdul Hakeem College, Melvisharam, Tamil Nadu, India.
*Corresponding Author
DOI No:

ABSTRACT:
Condensation of triethyleneteteramine with p-methyl benzaldehyde gives a novel quadridentate (N4) Schiff's base ligand. The complexes of this ligand with metal ions Fe(II),Ni(II) and Cu(II) have been synthesized. The Cu(II), Ni(II) complexes are square planar and the Fe(II) complex of the ligand has octahedral geometry. They have been characterized by elemental analysis, molar conductance, magnetic susceptibility, and IR, UV-Visible and thermal studies. Their ligand field parameters (Dq) and ligand field stabilization energy (LFSE) also have been calculated.
KEYWORDS:
Schiff’s base, Fe(II),Ni(II) and Cu(II) complexes, ligand field stabilization energy.
Cite:
A.K. Ibrahim Sheriff, S. Syed Shafi, G. Sasi Kumar, T.N. Balaji. Synthesis and Characterization of Novel Schiff Base Complexes of Some First Row Transition Metal Ions. Asian J. Research Chem. 5(6): June, 2012; Page 779-780.
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