Journal :   Asian Journal of Research in Chemistry

Volume No. :   7

Issue No. :  5

Year :  2014

Pages :   530-537

ISSN Print :  0974-4169

ISSN Online :  0974-4150


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Synthesis, Characterization and Study of Chemo-Physical Properties of New Ligands with Complexes of (Zn2+)



Address:   ThanaaAbdAlameerHelal1, AlaaAbadiHabeab2
1Chem. Dept., College of Education, Kufa University, Iraq
2Dept. of Pharmaceutical Chemistry, College of Pharmacy, University of Kufa., Iraq.
*Corresponding Author
DOI No:

ABSTRACT:
This study involved, synthesis of new three ligands from macro compound which contain aldamine or ketamine groups linked with azo groups in same molecule. macro ligands were synthesized by reacting of various diketone compounds such as (malonic acid, benzaldehyde derivatives ..) with hydrazine compounds or methylene di amine or azo compounds via condensation reaction or azotation reaction and coupling reaction to produce three ligands [(HIP), (HAT), (HIM)] of macro ligands and their complexes with zinc ion (II). The synthesized compounds were confirmed by (I.R ,UV –Vis, H.NMR, Atomic Absorption ,(C.H.N) –analysis), molar conductance and melting points.
KEYWORDS:
hydrazimine, complex of Zn, 4-coordination, diketon ligand, transition metals.
Cite:
ThanaaAbdAlameerHelal, AlaaAbadiHabeab. Synthesis, Characterization and Study of Chemo-Physical Properties of New Ligands with Complexes of (Zn2+). Asian J. Research Chem. 7(5): May 2014; Page 530-537.
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