Journal :   Asian Journal of Research in Chemistry

Volume No. :   7

Issue No. :  6

Year :  2014

Pages :   605-611

ISSN Print :  0974-4169

ISSN Online :  0974-4150


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Synthesis and Physicochemical Properties of New Poly dentate-Metal Complexes Derived from 2,6-diacetyl pyridine



Address:   Mahmoud N. Al-jibouri* ,Taghreed M. Musa,Sinan Midhat al-Bayati
Department of Chemistry, College of Science, Al-Mustansiriyah University, Baghdad, Iraq
*Corresponding Author
DOI No:

ABSTRACT:
A pent dentate ligand H2L was prepared by condensation reaction of one mole 2,6-diacetyl pyridine and two moles of 1,2-phenylene diamine,followed condensation with ethanol solution of salicyaldehyde The newl poly dentate (H2L) was identified on the basis of CHN micro elemental analysis, H and 13C NMR spectra. The manganese(II), cobalt (II),nickel(II),copper(II) and cadmium(II) have been isolated in the solid states and fully characterized on the basis of CHNM elemental analyses, FTIR, UV-Visible spectra, molar conductivity measurements and the magnetic moments. All the complexes have been assigned as octahedral geometry of general formula [ML] where M = Mn(II),Co(II), Ni(II), Cu(II) and Cd(II).
KEYWORDS:
Macro cyclic ligand, polydentate ligands type N4O2 system.
Cite:
Mahmoud N. Al-jibouri, Taghreed M. Musa, Sinan Midhat al-Bayati. Synthesis and Physicochemical Properties of New Poly dentate-Metal Complexes Derived from 2,6-diacetyl pyridine. Asian J. Research Chem. 7(6): June 2014; Page 605-611.
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