Journal :   Asian Journal of Research in Chemistry

Volume No. :   8

Issue No. :  11

Year :  2015

Pages :   690-692

ISSN Print :  0974-4169

ISSN Online :  0974-4150


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Synthesis of Copolymers of Acrylamide and Acrylonitrile via Redox Polymerization



Address:   Reena Bhadani1* and S. N. Bhadani2
1Department of Chemistry, Ranchi Women’s College, Ranchi
2P. G. Department Of Chemistry, Ranchi University, Ranchi
*Corresponding Author
DOI No: 10.5958/0974-4150.2015.00110.8

ABSTRACT:
he redox copolymerization of acrylonitrile with acrylamide in N,N - dimethylformamide (DMF) containing K2S2O8 and AgNO3 was carried out. The resulting copolymers were soluble in this solution. A white floppy mass was obtained, when poltmerizing solution was poured in cold methanol. The copolymers were formed taking different feed ratios of monomers and concentrations of the initiators at 600C. As the concentration of acrylamide increased in the feed ratio, copolymer yields consierably increased. The copolymerization was completely inhibited by 2, 2 – diphenyl – 1 – picrylhydrazyl suggesting a free radical reaction.
KEYWORDS:
Redox polymerization, acrylonitrile, acrylamide and copolymers.
Cite:
Reena Bhadani, S. N. Bhadani. Synthesis of Copolymers of Acrylamide and Acrylonitrile via Redox Polymerization. Asian J. Research Chem. 8(11): November 2015; Page 690-692.
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