Journal :   Asian Journal of Research in Chemistry

Volume No. :   10

Issue No. :  4

Year :  2017

Pages :   520-522

ISSN Print :  0974-4169

ISSN Online :  0974-4150


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Spectroscopic methods (IR, EPR and Electronic) for characterization of Homobinuclear 3D complexes



Address:   Nidhi Gupta
Department of Basic and Applied Sciences, Punjabi University, Patiala
*Corresponding Author
DOI No: 10.5958/0974-4150.2017.00085.2

ABSTRACT:
Tetra azadithio macrocyclic ligand has been used for the synthesis of macrocyclic complexes with copper metal salts. The stereochemistry, coordination behavior and structural analysis have been done by means of various physicochemical techniques i.e. elemental analysis, magnetic moment, molar conductance measurements and spectral studies such as IR, EPR and Electronic in DMSO/DMF solutions. The structures of the complexes have been determined with the help of spectroscopic as well as conductivity values and found to be six coordinated distorted octahedral geometry for the complexes. Molar conductance measurement revealed that the reported macrocyclic complexes were ionic and electrolytic in nature i.e. behaves as electrolyte.
KEYWORDS:
Macrocyclic, Spectroscopy, Conductance, Electrolyte, Sterochemistry.
Cite:
Nidhi Gupta. Spectroscopic methods (IR, EPR and Electronic) for characterization of Homobinuclear 3D complexes. Asian J. Research Chem. 2017; 10(4):520-522.
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