Journal :   Asian Journal of Research in Chemistry

Volume No. :   10

Issue No. :  4

Year :  2017

Pages :   483-485

ISSN Print :  0974-4169

ISSN Online :  0974-4150


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Extractive Spectrophotometric Determination of Ruthenium (III) Using Novel Salen Ligand

Address:   Ghanasham B. Sathe1*, Vikas V. Vaidya2, Ravidra G. Deshmukh3
1Dapoli Urban Bank Senior Science College, Dapoli, INDIA
2Ramnarain Ruia College, Mumbai, INDIA
3Konkan Dyanpeeth College, Karjat, INDIA
*Corresponding Author
DOI No: 10.5958/0974-4150.2017.00078.5

2-[(E)-N-(2—{[2-[(E)-[(2-hydroxyphenyl) methylildene] amino] phenyl} (methyl) amino} phenyl) carboximidoyl] phenol (HHMCP) was synthesized and employed to develop an extractive spectrophotometric method for the determination of Ru (III). The reagent forms a complex with Ru (III) and can be quantitatively extracted in Chloroform at pH = 4.0. The extracted species showed an absorption maximum at 505 nm. A systematic study of the extraction was carried out by varying the parameters like pH, reagent concentration and equilibration time.
Ruthenium (III), Extractive Spectrophotometry, solvent extraction.
Ghanasham B. Sathe, Vikas V. Vaidya, Ravidra G. Deshmukh. Extractive Spectrophotometric Determination of Ruthenium (III) Using Novel Salen Ligand. Asian J. Research Chem. 2017; 10(4):483-485.
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