Journal :   Asian Journal of Research in Chemistry

Volume No. :   10

Issue No. :  4

Year :  2017

Pages :   483-485

ISSN Print :  0974-4169

ISSN Online :  0974-4150


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Extractive Spectrophotometric Determination of Ruthenium (III) Using Novel Salen Ligand



Address:   Ghanasham B. Sathe1*, Vikas V. Vaidya2, Ravidra G. Deshmukh3
1Dapoli Urban Bank Senior Science College, Dapoli, INDIA
2Ramnarain Ruia College, Mumbai, INDIA
3Konkan Dyanpeeth College, Karjat, INDIA
*Corresponding Author
DOI No: 10.5958/0974-4150.2017.00078.5

ABSTRACT:
2-[(E)-N-(2—{[2-[(E)-[(2-hydroxyphenyl) methylildene] amino] phenyl} (methyl) amino} phenyl) carboximidoyl] phenol (HHMCP) was synthesized and employed to develop an extractive spectrophotometric method for the determination of Ru (III). The reagent forms a complex with Ru (III) and can be quantitatively extracted in Chloroform at pH = 4.0. The extracted species showed an absorption maximum at 505 nm. A systematic study of the extraction was carried out by varying the parameters like pH, reagent concentration and equilibration time.
KEYWORDS:
Ruthenium (III), Extractive Spectrophotometry, solvent extraction.
Cite:
Ghanasham B. Sathe, Vikas V. Vaidya, Ravidra G. Deshmukh. Extractive Spectrophotometric Determination of Ruthenium (III) Using Novel Salen Ligand. Asian J. Research Chem. 2017; 10(4):483-485.
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