Journal :   Asian Journal of Research in Chemistry

Volume No. :   13

Issue No. :  2

Year :  2020

Pages :   91-96

ISSN Print :  0974-4169

ISSN Online :  0974-4150


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Synthesis and Characterization of Novel Ag(I)-15C5 Complexes

Address:   Seema Chitlangia1, Rajeev Ranjan2*
1Univ. Department of Chemistry, Ranchi University, Ranchi
2Univ. Department of Chemistry, DSPM University, Ranchi
*Corresponding Author
DOI No: 10.5958/0974-4150.2020.00019.X

Crown ethers have been used for the various studies pertaining to extraction equilibrium constant, stability constant and for determination of some of the alkali and alkaline earth elements and other elements from p, d and f-block elements. Crown ethers have a significant coordination power towards silver ion. The present paper describes synthesis and characterization of novel Ag(I) complexes with 1,4,7,10,13,-pentaoxacyclooctadecane (15-crown-5 ether), having five donor ‘oxygen’ atoms. The organic salts used for complexation were salts of nitrophenols. Products were isolated from silver salts of all the three nitrophenols, 2-nitrophenol (ONPH), 2,4-dinitrophenol (DNPH) and 2,4,6-trinitrophenol (TNPH), having general formula of [Ag.L](Pic-), where L = 15C5 and Pic- = Picrate anion. The bonding pattern and structure of complexes were suggested from elemental analysis, molar conductivity, UV-Vis, IR, and 1H-NMR spectral analysis.
Seema Chitlangia, Rajeev Ranjan. Synthesis and Characterization of Novel Ag(I)-15C5 Complexes. Asian J. Research Chem. 2020; 13(2): 91-96.
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