Author(s):
Sharad Sharma, Ashok K. Patidar, Krishna K. Rathore, Ram C. Senwar Anita Mehta, Ajay K. Goswami
Email(s):
sharadsharma.chem@gmail.com
DOI:
10.5958/0974-4150.2015.00059.0 
Address:
Sharad Sharma, Ashok K. Patidar, Krishna K. Rathore, Ram C. Senwar Anita Mehta,
Ajay K. Goswami
Synthetic Organic Chemistry Laboratory, ML Sukhadia University, Udaipur, India. 313001
*Corresponding Author
Published In:
Volume - 8,
Issue - 5,
Year - 2015
ABSTRACT:
Bis hydroxytriazenes (1,1'-(sulfonyldibenzene-4,1-diyl)bis(3-hydroxy-3-phenyltriaz-1-en)) has been proposed as a sensitive and selective reagent for the spectrophotometric determination of Iron(III). The method is based on the formation of green coloured 1:1 complex by the reaction of Iron (III) with Bis hydroxytriazenes. Beer’s law is valid over the concentration range of 1×10-4 to 4.5×10-4. The coloured complex exhibit an absorption maximum at 410 nm with molar absorptivity of 45606.2 L mol-1cm-1and sendell sensitivity of 1.22 ng cm-2 the absorbance is found to increase linearly with increase in concentration of iron which are corroborated by the calculated correlation coefficient.
Cite this article:
Sharad Sharma, Ashok K. Patidar, Krishna K. Rathore, Ram C. Senwar Anita Mehta, Ajay K. Goswami. Analytical Application of 1, 1'-(Sulfonyldibenzene-4,1-diyl)bis(3-hydroxy-3-phenyltriaz-1-en) (BHDPT) in the Spectrophotometric Determination of Iron (III). Asian J. Research Chem 8(5): May 2015; Page 358-361. doi: 10.5958/0974-4150.2015.00059.0
Cite(Electronic):
Sharad Sharma, Ashok K. Patidar, Krishna K. Rathore, Ram C. Senwar Anita Mehta, Ajay K. Goswami. Analytical Application of 1, 1'-(Sulfonyldibenzene-4,1-diyl)bis(3-hydroxy-3-phenyltriaz-1-en) (BHDPT) in the Spectrophotometric Determination of Iron (III). Asian J. Research Chem 8(5): May 2015; Page 358-361. doi: 10.5958/0974-4150.2015.00059.0 Available on: https://ajrconline.org/AbstractView.aspx?PID=2015-8-5-10