Nernst’s distribution equation is employed when any of the solute present in the normal state in the two immiscible solvents, its distribution coefficients value can be calculated. Here it is also possible to use Nernst’s distribution equation for a solute when it is present in the normal state in miscible solvents, then we can also calculate distribution constant coefficients for any case of a solute. In this paper to mentioned for iodine itself distributing between the two miscible solvents such as cyclohexane and carbon tetrachloride. if the distribution ratio precisely known for miscible solvents then it will possible to study of distribution constants of Iodine in the two miscible solvents.
Cite this article:
Vikram R. Jadhav. Distribution of Iodine in two Miscible solvents. Asian J. Research Chem. 2020; 13(3):225-227. doi: 10.5958/0974-4150.2020.00043.7
1. Ariën S. Rustenburg, Justin Dancer, Baiwei Lin, Jianwen A. Feng, Daniel F. Ortwine, David L. Mobley, and John D. Chodera., Measuring experimental cyclohexane-water distribution coefficients for the SAMPL5 challenge, J Comput Aided Mol Des., 30 (11), 945–958 (2016).
2. Harry Medforth Dawson., CX - The solvent properties of mixed liquids in relation to the chemical characters and solvent properties of their components, J. Chem. Soc., Trans., 81, 1086-1097 (1902).
3. J Avraamides., The Iodine Propane Nitrile Water-System. Effects of Added Salts on Distribution Coefficient and Conductivity, Australian Journal of Chemistry, 40 (1), 209 – 214 (1987).
4. P. A. D. de Maine., Iodine Complexes in Inert Solvents. III. Iodine Complexes with Methanol, Ethanol, or Diethyl Ether in Carbon Tetrachloride, J. Chem. Phys. 26, 1192 (1957).
5. Raymond G. Wille and Mary L. Good., The Distribution of Iodine between Carbon Tetrachloride and Water and a Proposed Mechanism for Dilute, Aqueous Iodine Reactions, , J. Am. Chem. Soc, 79, 5, 1040-1043 (1957).
6. S. P. Mushtakova, G. V. Gerasimova & T. M. Varlamova., Distribution of iodine in the systems iodine-water-chloroform (diethyl ether) and iodine-potassium iodide-water-chloroform (diethyl ether), Journal of Analytical Chemistry, 64, pages 125 – 128 (2009).
7. Sean A. C. McDowell., The Distribution Constant of Iodine between Aqueous and Organic Phases. J. Chem. Educ, 77, 9, 1213 (2000).
8. Tatyana s. Tishakovaaa., Extraction in CCl4 of ionic associates of iodine iodide complexes with the cationic dye brilliant green, studia ubb chemia, lix, 1, p. 149-158 (2014).
9. Vikram R Jadhav, Y. R. Baste and D. D. Kajale., A solute associate or dissociate in miscible solvents, Asian Journal of Science and Technology, 09 (09), pp 8661-8666 (2018).
10. V. R Jadhav and Y. R. Baste., A process of solvent extraction: If distribution ratio exists for miscible solvents, J. Biol. Chem. Chron, 05 (03), pp 72-73 (2019).
11. V R Jadhav, et. al., Mathematical treatment to understanding the concentration terms, International Journal of Research and Review, 6 (1), p- 172-175 (2019).