ISSN

0974-4150 (Online)
0974-4169 (Print)


Author(s): Meghmala R. Sangvikar, Gayatri M. Phadnaik, Omprakash S. Chavan

Email(s): omprakashschavan@gmail.com

DOI: 10.52711/0974-4150.2021.00058   

Address: Meghmala R. Sangvikar1, Gayatri M. Phadnaik2, Omprakash S. Chavan1*
1P.G., Department of Chemistry, Badrinarayan Barwale College, Jalna - 431213, Maharashtra, India and Affiliated to Dr. Babasaheb Ambedkar Marathwada University, Aurangabad.
2Department of Chemistry, Institute of Science, Nagpur - 440012, Maharashtra, India and Affiliated to Rashtrasant Tukadoji Maharaj University, Nagpur.
*Corresponding Author

Published In:   Volume - 14,      Issue - 5,     Year - 2021


ABSTRACT:
The kinetics of DMSO (dimethylsulphoxide) assisted one pot cyclocondensation of bisanilino disulphide and 1,3-dicarbonyls has been investigated using spectral method. The kinetic measurements have been carried by varying media, temperature and concentration of the reactants. The assistance of DMSO is investigated. The order of reaction, effects of substituents with dicarbonyls on the rates and thermodynamic parameters has also been reported. First time reaction conditions are optimised for performing the cyclocondensation conveniently and rapidly. Probably mechanism has been proposed and order of reaction was determined on the basis of rate expression and was in agreement with second order rate equation, used for the determination of rate constants.


Cite this article:
Meghmala R. Sangvikar, Gayatri M. Phadnaik, Omprakash S. Chavan. Kinetics and Mechanism of Formation of 2,3-Disubstituted 1,4-Benzothiazines: One Pot DMSO Assisted Cyclocondensation of Bisanilino Disulphide and 1, 3-Dicarbonyls. Asian Journal of Research in Chemistry. 2021; 14(5):339-4. doi: 10.52711/0974-4150.2021.00058

Cite(Electronic):
Meghmala R. Sangvikar, Gayatri M. Phadnaik, Omprakash S. Chavan. Kinetics and Mechanism of Formation of 2,3-Disubstituted 1,4-Benzothiazines: One Pot DMSO Assisted Cyclocondensation of Bisanilino Disulphide and 1, 3-Dicarbonyls. Asian Journal of Research in Chemistry. 2021; 14(5):339-4. doi: 10.52711/0974-4150.2021.00058   Available on: https://ajrconline.org/AbstractView.aspx?PID=2021-14-5-7


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