Asian Journal of Research in Chemistry

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0974-4150 (Online)
0974-4169 (Print)


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Synthesis and Hydrolysis of Phosphoric Diamide without Seeking C-N-P Protonation by Acid

Author(s): Nitesh Goswami, Shashi Prabha

Email(s): nitesh_indu27@yahoo.com

DOI: Not Available

Address: Nitesh Goswami1 and Shashi Prabha2
1Gwalior Engineering College, Maharajpura, Airport Road, Gwalior (M.P.)
2School of Studies in Chemistry, Jiwaji University, Gwalior (M.P.)
*Corresponding Author

Published In:   Volume - 4,      Issue - 9,     Year - 2011

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ABSTRACT:
Phosphoric bis-(o-Methoxyphenyl amide) chloride, a C-N-P containing ester, on kinetic examination exhibited a rate maximum (via the Neutral form only) at 4.0 M-HCl and gave second-order kinetic rate coefficients during hydrolysis in the acid range, 0.01-7.0M HCl at 40( 0.5)0C. In the low acid range Zwitterionic species while in the higher acid range the undissociated form have been assessed as the major contributory reactive forms, undergoing bimolecular (Arrhenius Parameters) hydrolysis with P-N bond fission, The synthesis of the bis-amide was possible by the phosphorylation procedure and identification of the product was achieved by elemental analysis, and 31P NMR study in particular.


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Cite this article:
Nitesh Goswami, Shashi Prabha. Synthesis and Hydrolysis of Phosphoric Diamide without Seeking C-N-P Protonation by Acid. Asian J. Research Chem. 4(9): Sept, 2011; Page 1378-1380.

Cite(Electronic):
Nitesh Goswami, Shashi Prabha. Synthesis and Hydrolysis of Phosphoric Diamide without Seeking C-N-P Protonation by Acid. Asian J. Research Chem. 4(9): Sept, 2011; Page 1378-1380.   Available on: https://ajrconline.org/AbstractView.aspx?PID=2011-4-9-5


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Asian Journal of Research in Chemistry (AJRC) (ISSN: print-0974-4169, Online-0974-4150) is an international, peer-reviewed journal devoted to pure and applied chemistry. AJRC publishes Original Research Articles, Short Communications, Review Articles in all aspects of chemistry. Topics covered including the traditional areas of analytical, inorganic, organic, biochemistry, forensic, physical-theoretical chemistry as well as newer interdisciplinary areas such as agriculture, materials science, computational, medicine, spectroscopy, polymers, supramolecular, surface, chemical physics, biological, medicinal/ drugs, environmental and pharmaceutical chemistry.
The journal is published quarterly every year in last week of March, June, September and December. From January 2011, is monthly and shall be published every year in last week of Month.    
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