ISSN

0974-4150 (Online)
0974-4169 (Print)


Author(s): Noorussaba, Ishaat M. Khan, Afaq Ahmad, Bekir Ozcelik

Email(s): afaqahmad21@gmail.com , sabaamu@gmail.com

DOI: Not Available

Address: Noorussaba1, Ishaat M. Khan1, Afaq Ahmad1* and Bekir Ozcelik2
1Solid State Chemistry Lab, Department of Chemistry Aligarh Muslim University, Aligarh- 202002, India
2Cukurova University, Faculty of Sciences and Letters, Physics Department 01330, Balcalı- Adana/ Turkey
*Corresponding Author

Published In:   Volume - 6,      Issue - 11,     Year - 2013


ABSTRACT:
An experimental preparation and characterization of the composite system [CdHgI4:0.2AgI]:0.xCuI, (x = 0.2, 0.4, and 0.6 mol. wt. %), was investigated for superionic behavior. Powdered samples of different compositions containing x mol. wt. % CuI were synthesized by solid state reactions, using [CdHgI4:0.2AgI] mixed system as host. Analysis were carried out by x-ray powder diffraction, differential scanning calorimetry (DSC), differential thermal analysis (DTA) and thermal gravimetric analysis (TGA) techniques. These studies have revealed the formation of new substance having different phase transition temperature. Electrical conductivity measurements were carried out at frequency of 1 kHz in the temperature range 150° - 250°C by a Gen Rad 1659 RLC Digibridge. Activation energies for the system in eV both for the pre-transition and post-transition phase transformations are reported.


Cite this article:
Noorussaba, Ishaat M. Khan, Afaq Ahmad, Bekir Ozcelik. Preparation, ionic transport properties and characterization of [CdHgI4:0.2AgI]:0.xCuI fast ion conductor (x = 0.2, 0.4 and 0.6 mol. wt. %). Asian J. Research Chem. 6(11): November 2013; Page 996-1002.


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