ISSN

0974-4150 (Online)
0974-4169 (Print)


Author(s): Arjun G. Kalkhambkar, Rajappa S. K

Email(s): drrajappask@gmail.com

DOI: 10.52711/0974-4150.2022.00002   

Address: Arjun G. Kalkhambkar, Rajappa S. K*
Department of Chemistry, Karnatak Science College, Dharwad - 580001, Karnataka, India. *Corresponding Author

Published In:   Volume - 15,      Issue - 1,     Year - 2022


ABSTRACT:
Schiff base (E)-2-Furan-2-ylmethyleneamino acetic acid (FMAA) was prepared and investigated as inhibitor for corrosion protection of soft steel in hydrochloric acid medium. Mass change measurement and electrochemical technique employed for corrosion studies. Inhibitor protects the metal from corrosion up to maximum efficiency of 95.58 % at concentration of 0.004 M. Various activation parameters were calculated for corrosion of soft stell with different temperature. Soft-steel corrosion protection established via Langmuir adsorption isotherm from this; thermodynamical adsorption parameters like Kads, adsorption free energy of (?G0ads), are co-related to the soft steel deterioration protection. Tafel polarization curves reveal, FMAA exhibited mixed nature inhibitor. Modification of tested metal face morphology characterized using Scanning Electron Microscopy (SEM). Interaction of the FMAA molecules on soft steel face was confirmed through FT-IR analysis.


Cite this article:
Arjun G. Kalkhambkar, Rajappa S. K. Effect of (E)-2-furan-2-ylmethyleneaminoacetic acid on Corrosion protection of soft steel in HCl Environment. Asian Journal of Research in Chemistry. 2022; 15(1):10-8. doi: 10.52711/0974-4150.2022.00002

Cite(Electronic):
Arjun G. Kalkhambkar, Rajappa S. K. Effect of (E)-2-furan-2-ylmethyleneaminoacetic acid on Corrosion protection of soft steel in HCl Environment. Asian Journal of Research in Chemistry. 2022; 15(1):10-8. doi: 10.52711/0974-4150.2022.00002   Available on: https://ajrconline.org/AbstractView.aspx?PID=2022-15-1-2


REFERENCES:
1.    Mohammed AA. Mohamed MI. Corrosion and corrosion control of mild steel in concentrated H2SO4 solutions by a newly synthesized glycine derivative. Corrosion Science, 2011;53:873-885.https://doi.org/10.1016/j.corsci.2010.10.022
2.    Narayana H. Praveen BM. Prasanna. Deep A. Electrochemical and Adsorption Studies of Telmisartan for Mild Steel in Acidic Medium. J Bio and Tribo-Corros, 2019; 5:40. https://doi.org/10.1007/s40735-019-0231-y
3.    Praveen BM. Prasanna BM, Narayana H. Shivakeshava Kumar. Jagadeesh MR, Experimental and Theoretical Studies on Inhibition Effect of the Praziquantel on Mild Steel Corrosion in 1 M HCl. J Bio and Tribo-Corros 2018;4:21. https://doi.org/10.1007/s40735-018-0137-0
4.    Rajappa SK. Praven BM. Venkatesha TV. Chemical and electrochemical studies of ranitidine as a corrosion inhibitor for mild steel in hydrochloric acid medium. Int Res J of Chem. 2014; 01:10-17.
5.    Ayatia NS. Khandandela S. Momenia M. Moayeda MH. Davoodib A. Rahimizadehc M, Inhibitive effect of synthesized 2-(3-pyridyl)-3,4-dihydro-4-quinazolinone as a corrosion inhibitor for mild steel in hydrochloric acid. Mat Chem and Phys. 2011; 126:873-879. https://doi.org/10.1016/j.matchemphys.2010.12.023
6.    Arockiasamy P, Queen Rosary Sheela X, Thenmozhi G, Franco M, Wilson Sahayaraj J, Jaya Santhi R, Evaluation of Corrosion Inhibition of Mild steel in 1M hydrochloric acid solution by Mollugo cerviana. Int J of Corrs 2014; 1-7. http://dx.doi.org/10.1155/2014/679192
7.    Rajeshwari M. Eco friendly synthesis of N'-Arylidene-2-((7-bromo-2-methylpyrido[2,3-B]pyrazin-3-yl)oxy)acetohydrazides. Asian J. Research Chem. 2018; 11(2):279-281. doi: 10.5958/0974-4150.2018.00052.4
8.    Benita Sherine H. Jency Angela A. Rajendran S. O-Nitro Phenol as a Corrosion Inhibitor for Carbon Steel. Asian J. Research Chem. 2011; 4(4): 629-635.
9.    Ali Doner. Ramazan S. Muzaffer O.  Gulfeza. Experimental and theoretical studies of thiazoles as corrosion inhibitors for mild steel in sulphuric acid solution. Corrosion Science. 2011; 53:2902-2913. https://doi.org/10.1016/j.corsci.2011.05.027
10.    Aljourani J, Raeissi K, Golozar MA. Benzimidazole and its derivatives as corrosion inhibitors for mild steel in 1M HCl solution. Corrosion Science. 2009; 51:1836–1843. https://doi.org/10.1016/j.corsci.2009.05.011
11.    Obagboye FO. Olasehinde E F. Oyewumi M. Tomilawo BA. Instrumental Investigations studies of green Inhibition Potential (Case Study: Zea mays cobs extracts on mild steel in Acidic Medium). Asian J. Research Chem. 2020; 13(2):146-150. doi: 10.5958/0974-4150.2020.00029.2
12.    Jeetendra B. Pramod Jain. Investigation of Mentha spicata extract as Green Corrosion Inhibitor for Mild Steel in 2M Sulphuric Acid Medium. Research J. Pharm. and Tech 2018; 11(10): 4627-4634. doi: 10.5958/0974-360X.2018.00846.6
13.    Vasantha Jothi R. Maheshwari P. Saratha R. Senthil Vadivu D. A study on Inhibitive action of Bauhinia racemosa Lam. Extract as Green Corrosion inhibitor for Mild steel in Hydrochloric acid medium. Asian J. Research Chem. 2017; 10(5): 611-615. DOI:  10.5958/0974-4150.2017.00102.X
14.    Mothilal KK. Comparative study of green corrosion inhibition effect on mild steel in different acid medium by Laburnum waterier Vossii leaves extract. Asian J. Research Chem. 2018; 11(2):253-261. doi: 10.5958/0974-4150.2018.00048.2
15.    Messaoud G. Louiza Z. Soufiane B. Elyacout C. Khaled. C. Inhibitive and Adsorption behaviour of date Palm Hemicellulose on Mild Steel Corrosion in Sulfuric Acid Media. Asian J. Research Chem. 2019; 12(6):303-306. doi: 10.5958/0974-4150.2019.00055.5
16.    Vasantha Jothi R. Maheshwari P. Saratha R. Senthil Vadivu D. A study on Inhibitive action of Bauhinia racemosa Lam. Extract as Green Corrosion inhibitor for Mild steel in Hydrochloric acid medium. Asian J. Research Chem. 2017; 10(5): 611-615. doi: 10.5958/0974-4150.2017.00102.X
17.    Issaadi S, Douadi T, Zouaoui A, Chafaa, Khan MA, Bouet G. Novel thiophene  symmetrical Schiff base compounds as corrosion inhibitor formild steel in acidic media. Corrosion Science. 2011; 53:1484-1488.  https://doi.org/10.1016/j.corsci.2011.01.022
18.    Ansari KR. Quraishi MA. Ambrish Singh. Schiff’s base of pyridyl substituted triazoles as new and effective corrosion inhibitors for mild steel in hydrochloric acid solution. Corrosion Science. 2014; 79:5-15.   https://doi.org/10.1016/j.corsci.2013.10.009
19.    Stanly Jacob K. Geetha Parameswaran. Corrosion inhibition of mild steel in hydrochloric acid solution by Schiff base furoin thiosemicarbazones. Corrosion Science. 2010; 52:224-228. https://doi.org/10.1016/j.corsci.2009.09.007
20.    Soltani N, Behpour M, Ghoreishi SM, Naeimi H. Corrosion inhibition of mild steel in hydrochloric acid solution by some double Schiff bases. Corrosion Science. 2010; 52:1351-136. https://doi.org/10.1016/j.corsci.2009.11.045
21.    Shanbhag AV. Venkatesha TV.Prabhu RA. Rajesh G K. Kulkarni M. (2008) Corrosion inhibition of mild steel in acidic medium using hydrazide derivatives. J App Electrochem. 2008; 38:279-287. https://doi.org/10.1007/s10800-007-9436-8  
22.    Priyanka Singh, Quraishi MA. Corrosion inhibition of mild steel using Novel Bis Schiff’s Bases as corrosion inhibitor. Electrochemical and Surface Measurement. 2016; 86:114-124. https://doi.org/10.1016/j.measurement.2016.02.052
23.    Arjun G K. Rajappa SK, Janakunavar G, Sujatha K. Influence of furfuraldehyde derivatives as inhibition of mild steel in hydrochloric acid solution. J Mater Environ Sci. 2020; 11:1626-1641
24.    Bin Xu, Ying Liu, Xiaoshuang Yin, Wenzhong Yang, Yizhong Chen. Experimental and theoretical study of corrosion inhibition of 3-pyridinecarbozalde thiosemicarbazone for mild steel in hydrochloric acid. Corrosion Science. 2013; 74:206-213 https://doi.org/10.1016/j.corsci.2013.04.044
25.    Larabia L, Harek Y, Benali O, Ghalemb S. Hydrazide derivatives as corrosion inhibitors for mild steel in 1M HCl. Progress in Organic Coatings. 2005; 54:256-262. https://doi.org/10.1016/j.porgcoat.2005.06.015
26.    Fouad B, Charafeddine Jama, Bouchaib M, Hassan El Attari, Lamia El Kadi , Mounim Lebrini, Michel Traisnel, Michel Lagrenee. Corrosion control of mild steel using 3,5bis(4-methoxyphenyl)-4-amino-1,2,4- triazole in normal hydrochloric acid medium. Corrosion Science. 2009; 51:1628-1635. https://doi.org/10.1016/j.corsci.2009.04.009
27.    Tharini K. Raja K. Senthilkuma AN. 1-methyl-3-ethyl-2, 6-diphenyl piperidin-4-one oxime as an Inhibitor for Mild Steel Corrosion in H2SO4 medium. Asian J. Research Chem. 2015; 8(10): 630-634. doi: 10.5958/0974-4150.2015.00100.5
28.    Mirghasem Hosseini, Stijn F.L. Mertens, Mohammed G. Mohammed R. Arshadi. Asymmetrical Schiff bases as inhibitors of mild steel corrosion in sulphuric acid medium. Mat Chem and Phys. 2003; 78:800-808 https://doi.org/10.1016/S0254-0584(02)003905
29.    Ashassi-Sorkhabia H, Shaabanib B, Seifzadeha. Corrosion inhibition of mild steel by some schiff base compounds in hydrochloric acid. Applied Surface Science. 2005; 239:154-16. https://doi.org/10.1016/j.apsusc.2004.05.143
30.    Zcan MO, Dehri M Erbil. Organic sulphur-containing compounds as corrosion inhibitors for mild steel in acidic media Correlation between inhibition efficiency and chemical structure. Applied Surface Science. 2004; 236:155-164. https://doi.org/10.1016/j.apsusc.2004.04.017
31.    Ostovari A, Hoseinieh SM, Peikari M, Hasemi SJ. Corrosion inhibition of mild steel in 1M HCl solution by henna extract: a comparative study of the inhibition by henna and its constituents (Lawsone, Gallic acid, α-d-Glucose and Tannic acid). Corrosion Science. 2009; 51:1935–1949
32.    Diwan Singh R. Shiv Darshan M. Surfactants as Corrosion Inhibitors for Carbon Steel in Hydrochloric acid Solution. Asian J. Research Chem.  2012; 5(4): 520-525.  https://ajrconline.org/AbstractView.aspx?PID=2012-5-4-15
33.    Ateya B, El-Anadauli B, F El. Nizamy. The adsorption of thiourea on mild steel. Corrosion Science. 1984; 24:509.
34.    Negm N A, Elkholy YM, Zahran MK, Tawfik SM. Corrosion inhibition efficiency and surface activity of benzothiazol-3-ium cationic Schiff base derivatives in hydrochloric acid. Corroson Science. 2010; 52:3523–3536   https://doi.org/10.1016/j.corsci.2010.07.001
35.    Subha R. Saratha R. Corrosion Inhibition and Adsorption Properties of African marigold for the Corrosion of Mild Steel in Hydrochloric acid. Asian J. Research Chem. 2012; 5(3): 390-396. https://ajrconline.org/AbstractView.aspx?PID=2012-5-3-16
36.    Kaan C Emregu, Orhan Atakol Ankara. Schiff bases of increasing complexity as mild steel corrosion inhibitors in 2M HCl. Corrosin Science. 2007; 49:2800–2814. https://doi.org/10.1016/j.corsci.2007.02.002
37.    Hosseini S M A, Azimi A. The inhibition of mild steel corrosion in acidic medium by 1- methyl-3-pyridin-2- yl-thiourea. Corrosion Science. 2009; 51:728–732. https://doi.org/10.1016/j.corsci.2008.11.019
38.    Behpour M, Ghoreishi SM, Mohammadi N, Soltani N, Salavati-Niasari M. Investigation of some Schiff base compounds containing disulfide bond as HCl corrosion inhibitors for mild steel. Corrosion Science. 2010; 52:4046–4057.
39.    Wang HL. Liu RB. Xin J. Inhibiting effect of some mercapto-triazole derivatives on the corrosion of mild steel in 1M HCl medium. Corrosion Science. 2004; 46: 24-55.
40.    Mustafa Kamel Joudah. Inhibition impact Investigation of ((5-thiophen-2-ylmethylene) amino)-2-mercapto-1,3,4-thiadiazole on mild steel corrosion in hydrochloric acid. Research J. Science and Tech. 2017; 9(2): 267-271. doi: 10.5958/2349-2988.2017.00048.1
41.    Praveen BM. Venkatesha TV. Metol as Corrosion Inhibitor for Steel. Int J Electrochem Sci. 2009; 4:267- 275
42.    Manohar RR. Rajappa SK. Corrosion inhibition effect of Cycas revoluta leaves extracton corrosion of soft-cast steel in hydrochloric acid medium. Electrochemical Science Advances. 2021; 1 (1): 1-14. doi.org/10.1002/elsa.202100059
43.    Bahrami MJ, Hosseini, Pilvar P. Experimental and theoretical investigation of organic compounds as inhibitors for mild steel corrosion in sulfuric acid medium. Corrosion Science. 2010; 52:2793–2803.
44.    Manohar RR. Rajappa SK. Praveen BM. Barath DK. Investigation of Dolichandra unguis-cati leaves extract as a corrosion inhibitor for mild steel in acid medium. Current Research in Green and Sustainable Chemistry. 2021, 100113. https://doi.org/10.1016/j.crgsc.2021.100113.
45.    Manov S, Noli F, Lamazouere AM, Aries L. Surface treatment for zinc corrosion protection by a new organic chelating reagent. J Appl Electrochem. 1999; 29: 995-1003

Recomonded Articles:

Author(s): Arun Kumar, Vinita Gupta, Sanchita Singh, Y.K. Gupta

DOI: 10.5958/0974-4150.2017.00038.4         Access: Open Access Read More

Author(s): Sindhu. T. J, Akhilesh K. J, Anju. Jose, Binsiya K. P, Blessy Thomas, Elizabeth Wilson

DOI: 10.5958/0974-4150.2020.00026.7         Access: Open Access Read More

Author(s): Kadhiravansivasamy, S. Sivajiganesan, T. Periyathambi, V. Nandhakumar, M. Pugazhenthi

DOI: 10.5958/0974-4150.2017.00016.5         Access: Open Access Read More

Author(s): Kishore Kumar Valluri, Tejeswara Rao Allaka, I V Kasi Viswanath, Nagaraju PVVS

DOI: 10.5958/0974-4150.2018.00111.6         Access: Open Access Read More

Author(s): Ali Boumeftah, Abdelkader Belmokhtar, Abdelghani Benyoucef

DOI: 10.5958/0974-4150.2021.00012.2         Access: Open Access Read More

Author(s): K. Juliet Gnana Sundari, C. Joseph Kennady, S. Rajendran

DOI:         Access: Open Access Read More

Author(s): Adekunle Adetukasi, Ajayi Babatunde Olasunkanmi, Okoronkwo Afamefuna Elvis

DOI: 10.5958/0974-4150.2019.00053.1         Access: Open Access Read More

Author(s): Fatiha Chelgham, Noureddine Bouzid, Mokhtar Saidi, Amira Ouakkaf, Adel Taabouche, Souhila Boudjema, Hanane Largot, Abdellatif Mamanou, Noura Meddoura

DOI: 10.5958/0974-4150.2021.00013.         Access: Open Access Read More

Author(s): C.V. Deepaa, V.G. Vasudha, T. Sathiyapriya

DOI:         Access: Open Access Read More

Author(s): Jeetendra Bhawsar, P.K. Jain, Preeti Jain, Mukta Rani Bhawsar

DOI:         Access: Open Access Read More

Author(s): M. Yadav, Sushil Kumar, Abu Nasar, Sunil Kumar

DOI:         Access: Open Access Read More

Author(s): Faouzi Zahi, Fethi Medjani, Mohamed Djidel, Abdelmalek Drouiche

DOI: 10.52711/0974-4150.2021.00033         Access: Open Access Read More

Asian Journal of Research in Chemistry (AJRC) is an international, peer-reviewed journal devoted to pure and applied chemistry..... Read more >>>

RNI: Not Available                     
DOI: 10.5958/0974-4150 

Popular Articles


Recent Articles




Tags