ISSN

0974-4150 (Online)
0974-4169 (Print)


Author(s): Md.Kudrat-E-Zahan, Hiroshi Sakiyama

Email(s): Kudrat.chem@ru.ac.bd

DOI: Not Available

Address: Md.Kudrat-E-Zahan1* and Hiroshi Sakiyama2
1Associate Professor, Dept. of Chemistry, Faculty of Science, Rajshahi University, Rajshahi-6205, Bangladesh
2Department of Material and Biological Chemistry, Faculty of Science, Yamagata University, Japan
*Corresponding Author

Published In:   Volume - 7,      Issue - 3,     Year - 2014


ABSTRACT:
The aerobic epoxidation of alkenes with an aldehyde as a co-reagent is an efficient and useful method for the production of fine chemicals. In this study, the interactions of molecular oxygen with its each component are measured. Dichloromethane is choosen as solvent. Pivalaldehyde, 2-ethylbutyraldehyde and heptanal are chosen as aldehydes. Aldehydes having tertiary and secondary carbon next to carbonyl carbon are found to produce ultraviolet contact charge transfer (CCT) absorption band with molecular oxygen (O2).


Cite this article:
Md.Kudrat-E-Zahan, Hiroshi Sakiyama. ectroscopic and Theoretical Investigation on the Charge Transfer Complex of Aldehydes with Molecular Oxygen Concerning Epoxidation of Alkenes. Asian J. Research Chem. 7(3): March 2014; Page 278-280.


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