ABSTRACT:
Ruthenium (III) catalysed oxidation of L-Isoleucine by alkaline permanganate were studied spectophotometrically over the range 25 = t =35oC, I=0.5 , 2 x 10-4 = oxidant =10 x 10-4, 1 x 10-3= substrate= 5 x 10-3 , 1 x 10-7 =catalyst = 5 x 10-7. The reaction is first order with respect to oxidant, substrate and catalyst. The ?H?,?S? values were calculated to be 48±9.36 KJ/mol and -134.2 ±23.2 JK-1/mol.
Cite this article:
S. Panda, P. Mohanty. Ruthenium(III)Catalyzed Oxidation of L-Isoleucine by Alkaline KMnO4: A Kinetic and Mechanistic Study. Asian J. Research Chem. 5(9): September, 2012; Page 1182-1185.
Cite(Electronic):
S. Panda, P. Mohanty. Ruthenium(III)Catalyzed Oxidation of L-Isoleucine by Alkaline KMnO4: A Kinetic and Mechanistic Study. Asian J. Research Chem. 5(9): September, 2012; Page 1182-1185. Available on: https://ajrconline.org/AbstractView.aspx?PID=2012-5-9-17