ISSN

0974-4150 (Online)
0974-4169 (Print)


Author(s): Alaka Das, P. Mohanty

Email(s): gulualaka@gmail.com

DOI: Not Available

Address: Alaka Das and P. Mohanty
Department of Chemistry, Utkal University, Vani Vihar, Bhubaneswar, Odisha
*Corresponding Author

Published In:   Volume - 6,      Issue - 4,     Year - 2013


ABSTRACT:
The kinetics of Copper(II), Nickel(II) and Zinc(II) catalysed oxidation of Ornithine by Permanganate in alkaline medium at a constant ionic strength has been studied spectrophotometrically. The reaction between permanganate and ornithine in alkaline medium exhibits 2:1 stoichiometry (KMnO4, Ornithine). The reaction shows first order dependence on the concentration of permanganate and each catalyst and less than unit order dependence on the concentration of ornithine and alkali. No effect of added products and dielectric constants has been observed. Investigation at different temperatures allowed the determination of the activation parameters with respect to slow step of the proposed mechanism. A mechanism involving the formation of a complex between catalyst and substrate has been proposed.


Cite this article:
Alaka Das, P. Mohanty. Kinetics Study of Copper (II), Nickel (II), Zinc (II) Catalytic Oxidation of Ornithine Hydrochloride by Alkaline Potassium Permanganate. Asian J. Research Chem. 6(4): April 2013; Page 305-318.


Recomonded Articles:

Author(s): Kishu Tripathi, Shobha Kulshreshtha

DOI:         Access: Open Access Read More

Author(s): Nandkishor Telkapalliwar, Vidyadhar Shivankar

DOI: 10.5958/0974-4150.2017.00009.8         Access: Open Access Read More

Author(s): R Manoj Prabakaran, V Niranjan, VM Seenivasan, S Thenesh Kumar

DOI:         Access: Open Access Read More

Author(s): Gopalasatheeskumar K, Ariharasiva Kumar G, Sengottuvel T, Sanish Devan V, Srividhya V

DOI: 10.5958/0974-4150.2019.00062.2         Access: Closed Access Read More

Author(s): Salifou Karimoune Fadjimata, Adamou Rabani, Adamou Hassane Hassane, Ayouba Mahamane Abdoulkadri

DOI: 10.5958/0974-4150.2020.00027.9         Access: Closed Access Read More

Author(s): S. Begam, F. Hussain, Jaibir Singh, A. K. Sharma, D. S. N. Prasad

DOI: 10.5958/0974-4150.2018.00110.4         Access: Open Access Read More

Author(s): P. Varshney, Vinod Kumar, S.K. Gururani

DOI:         Access: Open Access Read More

Author(s): Adekunle Adetukasi, Ajayi Babatunde Olasunkanmi, Okoronkwo Afamefuna Elvis

DOI: 10.5958/0974-4150.2019.00053.1         Access: Closed Access Read More

Author(s): Bizuneh Adinew, Tesfahun Kebede, Benebru Shimelis

DOI:         Access: Open Access Read More

Author(s): Merlin NJ Parthasarathy V, Manavalan R, Devi P, Meera R

DOI:         Access: Open Access Read More

Author(s): A. V. L. N. S. H. Hariharan, K. C. Purnima

DOI: 10.5958/0974-4150.2018.00035.4         Access: Open Access Read More

Author(s): Nilesh Patel, Shailesh Shah, Ishwarsinh Rathod, Dhaval Patel, Biraju Patel

DOI:         Access: Open Access Read More

Author(s): C. Buvana, M. Sukumar, Sijamol, Udhyakumri, Hannath

DOI:         Access: Open Access Read More

Asian Journal of Research in Chemistry (AJRC) is an international, peer-reviewed journal devoted to pure and applied chemistry..... Read more >>>

RNI: Not Available                     
DOI: 10.5958/0974-4150 

Popular Articles


Recent Articles




Tags