ISSN

0974-4150 (Online)
0974-4169 (Print)


Author(s): A. K. Singh, L. K. Tiwari

Email(s): anilkumar2_singh@yahoo.com

DOI: 10.5958/0974-4150.2020.00041.3   

Address: A. K. Singh1, L. K. Tiwari2
1Department of Chemistry, Teerthanker Mahaveer University, Moradabad, India.
2Dpartment of Mathematics, Teerthanker Mahaveer University, Moradabad, India.
*Corresponding Author

Published In:   Volume - 13,      Issue - 3,     Year - 2020


ABSTRACT:
The kinetics of alkaline hydrolysis of propyl Hexanote has been studied as a base catalyst under second order reaction at the temperature range from 20 to 40?C.The reaction rate was measured volumetrically over a range of water-propanol mixed solvent(30-70% v/v).The reaction rate was found to be increased with increasing temperature at all composition of reaction mixture. Thermodynamic parameter was calculated. The non-linear increase in free energy with mole% suggests the specific salvation taking place in reaction media. The value of iso-kinetic temperature is more than 300 which indicates strong solvent-solute interaction in reaction media.


Cite this article:
A. K. Singh, L. K. Tiwari. Study of Solvent effect of Protic solvent on Solvolysis of Hexanoate ester and Activation parameters. Asian J. Research Chem. 2020; 13(3):216-218. doi: 10.5958/0974-4150.2020.00041.3


REFERENCE:
1.    Singh A K. Arjuman Bano, “Kinetics and Solvent effect on Aquo-dipolar protic organic-solvent system of Hexanoate ester.” Asian journal of Research in Chemistry, 12(6) Nov 2019, pp 341-344
2.    Sharma Sangita et al. Kinetic study of specific base catalysed hydrolysis of Ethyl Acrylate in water-Ethanol binary system. Russian Journal of Physical Chemistry A. Vol. 87, No. 5, 2013. Pp730-736
3.    Singh A K., Kinetics and solvent effect on activation parameter of aquo-propanol solvent system for acid catalyzed solvolysis of propyl formate. International Journal of Chemical Science, vol-3, issue-4, July, 2019 pp85-88
4.    Singh A K., Solvent effect and kinetics on solvolysis of propyl formate in water-propanol solvent mixture. International Journal of Chemical Science, Vol-3, Issue-4, July, 2019 pp82-84
5.    Magda F Fathalla., Kinetics of reaction of 2-chloro-quinosalin with Hydroxide ion in CAN- H2O and DMSO- H2O binary solvent mixture,” Journal of Solution Chemistry, 40, 1258-70, 2011
6.    Singh AK. Arjuman Bano., Solvent effect and kinetics on ethyl benzoate in aqueous solvent system. International Journal of Chemical Science, Volume 3; Issue 5; September 2019; Page No. 26-28
7.    Singh A K., Kinetics and solvent effect on activation parameter of aquo-propanol solvent system for acid catalyzed solvolysis of propyl formate. International Journal of Chemical Science ISSN:2523-2843, Vol-3, Issue-4, July, 2019 pp85-88
8.    Wynne-Jones W. F. K, and Eyring, H: “The Absolute Rate of Reaction in condense Phase”. J. Chem. Phys. 3, 492-502, 1935.
9.    Hughes E.D. and Ingold C.K, “Mechanism of substitution at saturated carbon atom part IV, A discussion of constitution and solvent effect on mechanism, kinetics, velocity, and orientation of substitution”. J Chem. Soc 1935, 244- 255
10.    Bano Arjuman and Singh A K., “A Kinetic study of dipolar protic solvent in alkaline hydrolysis of ethyl nicotinate in water-ethanol media-A Solvent effect, “Journal of Ultra-Chemistry, Volume-13(6) Nov,2017, pp-145-150.
11.    Singh A. K., Influence of solvent on solvolysis of ethyl cinnamate in water-acetone mixed solvent system. Chemical Sciences Journal 2017ISSN 2150-3494: 1, 10.4172/2150- Volume 8. Issue 1.1000150.
12.    Wolford R K: “Kinetics of acid catalised hydrolysis of Acetal in dimethylsulfoxide-water solvent system at 15,25 and 35C.” Phys Chem, 68, 3392 1964
13.    Singh AK et al. Kinetics and Solvent effect on Aquo-dipolar protic organic-solvent system of Hexanoate ester.” Asian Journal of Research in Chemistry, 12(6) Nov 2019, pp 341-344
14.    Wynne-jones W F K and Eyring H., The Absolute rate of reaction in condense phases” Journal of Chemical Physics 3; 492-502.
15.    Elsemogy, M.M., Abu Elamayem, M.S., and Mussa, M.N.H: Z. Physik chem (Neuetold) 94, 69, 1975
16.    Singh AK.  Arjuman Bano., Solvent effect and kinetics on ethyl benzoate in aqueous solvent system. International Journal of Chemical Science, ISSN:2523-2843, Volume 3; Issue 5; September 2019; Page No. 26-28
17.    Lefler J.E. “Entropy relationship and implication for organic chemistry.” J. Org. Chem., 20, 1201, 1955
18.    Singh AK.  Arjuman Bano., Solvent effect and kinetics on ethyl benzoate in aqueous solvent system. International Journal of Chemical Science, ISSN:2523-2843, Volume 3; Issue 5; September 2019; Page No. 26-28

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