Sharad Sankhe, Ramesh Yamgar, Umesh N. Pol
Sharad Sankhe1, Ramesh Yamgar1 and Umesh N. Pol2
1Chemistry Research Laboratory, Patkar College, Goregaon (W), Mumbai 400 062.
2Department of Chemistry Willingdon College, Sangli, Maharashtra.
Volume - 4,
Issue - 12,
Year - 2011
The kinetics of oxidation of the Schiff base 2-hydroxy - 1 - Naphthalidene anil and substituted anils such as 2’ – methoxy - 2 - hydroxy - 1 - naphthalidene anil, 3’ – Methoxy - 2 - Hydroxy - 1 - Naphthalidene anil and 4’ – Methoxy - 2 - Hydroxy - 1- Naphthalidene anil by Ce (IV) as oxidant in aqueous sulphuric acid medium. The kinetic study is carried out by using various concentrations of oxidants and the substrates, which is found to be the first order reaction. A suitable plaussible mechanism has been suggested on the basis of kinetic results.
Cite this article:
Sharad Sankhe, Ramesh Yamgar, Umesh N. Pol. Kinetics of Oxidation of 2-Hydroxy-1-Naphthalidene Anil and Substituted Anils by Ce4+ Ce3+ Redox System in Aqueous Sulphuric Acid Medium. Asian J. Research Chem. 4(12): Dec., 2011; Page 1861-1863.