ISSN

0974-4150 (Online)
0974-4169 (Print)


Author(s): P Jayaseelan, S Prasad, R Rajavel

Email(s): drrajavel@rediffmail.com

DOI: Not Available

Address: P Jayaseelan, S Prasad and R Rajavel*
Department of Chemistry, Periyar University, Salem-11, TamilNadu
*Corresponding Author

Published In:   Volume - 3,      Issue - 2,     Year - 2010


ABSTRACT:
The tetradentate Schiff base ligand was prepared by condensation of 2-aminobenzaldehyde with o-phenylenediamine. The synthesized complex has been studied by using cyclic voltammetry and DNA cleavage studies. The resulting voltammogram consists of a single quasi-reversible one electron transfer attribute to couple [Cu(II)L]/[Cu(I)L]. Trends in cathodic peak potential (Epc) values are observed which can be correlated with electron effects of Schiff base ligand, changes with basis of liquid groups are determinant for electrochemical trends. The interaction of Cu(II) complex with Calf Thymus DNA has been studied by using absorption, viscosity and cyclic voltammetry. Cyclic voltammetry studies reveal that the complex prefer to bind to DNA in Cu(II) rather than(I) oxidation state.


Cite this article:
P Jayaseelan, S Prasad, R Rajavel. Redox Behavior and DNA Cleavage Studies of Copper (II) Schiff Base Complex Derived From 2-Aminobenzaldehyde. Asian J. Research Chem. 3(2): April- June 2010; Page 389-394.


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