ISSN

0974-4150 (Online)
0974-4169 (Print)


Author(s): Zamzam Taher Omar (Al-Ahdal), Shivaji Jadhav, Rashmi Pathrikar, Shaikh Uzma, Megha Rai

Email(s): dr.shivaji1985@gmail.com

DOI: 10.52711/0974-4150.2022.00034   

Address: Zamzam Taher Omar (Al-Ahdal)1, Shivaji Jadhav2*, Rashmi Pathrikar3, Shaikh Uzma1, Megha Rai1
1Department of Chemistry, Dr. Rafiq Zakaria College for Women, Aurangabad - 431001, MS, India.
2Department of Chemistry, Tarai College Paithan, Aurangabad, MS, India.
3Department of Chemistry, Rajshri Shahu College, Pathri, Aurangabad, MS, India.
*Corresponding Author

Published In:   Volume - 15,      Issue - 3,     Year - 2022


ABSTRACT:
Present research work describes the successful development of inner transition metal ion complexation, magnetic susceptibility study, thermodynamic parameters and biological applications of synthesized organic ligand. Stability constant Order of developed metal complexes of N-[-(4-chlorophenyl) methylene] isonicotinohydrazide was found as follows La(III) > Ce(III) > Sm(III). Positive µeff clearly indicates paramagnetic nature of developed complexes. During thermodynamic parameter examination we found stability constants for complexes decrease with an increasing temperature, indicating that the composition equilibrium is exothermic in nature. Also ?H and ?G were negative for all of the systems which suggested that all of the reactions were exothermic. The ?S found positive for most of the complexes which indicate in metal-ligand binding process is entropy favourable. In antimicrobial evaluation, we observed that Sm+3 metal complexes of (N-[(E)-(4-chlorophenyl) methylene] isonicotinohydrazde) exhibit superior property specifically against gram negative bacteria with respect to organic ligand.


Cite this article:
Zamzam Taher Omar (Al-Ahdal), Shivaji Jadhav, Rashmi Pathrikar, Shaikh Uzma, Megha Rai. Complexation, Bio-evaluation, Magnetic Susceptibility and Thermodynamic study of Newly Synthesized Pharmacologically active Schiff base with La(III), Ce(III) and Sm(III). Asian Journal of Research in Chemistry. 2022; 15(3):200-6. doi: 10.52711/0974-4150.2022.00034

Cite(Electronic):
Zamzam Taher Omar (Al-Ahdal), Shivaji Jadhav, Rashmi Pathrikar, Shaikh Uzma, Megha Rai. Complexation, Bio-evaluation, Magnetic Susceptibility and Thermodynamic study of Newly Synthesized Pharmacologically active Schiff base with La(III), Ce(III) and Sm(III). Asian Journal of Research in Chemistry. 2022; 15(3):200-6. doi: 10.52711/0974-4150.2022.00034   Available on: https://ajrconline.org/AbstractView.aspx?PID=2022-15-3-3


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