Asian Journal of Research in Chemistry

ISSN

0974-4150 (Online)
0974-4169 (Print)


Submit Article

Kinetics and Mechanism of HgCl2 Catalysed Oxidation of Organic Sulfides by Permanganate in Non-Aqueous Medium

Author(s): K.P. Srivastava, Sanjay Kumar Rai

Email(s): gscdrkpsritprin@gmail.com

DOI: Not Available

Address: K.P. Srivastava* and Sanjay Kumar Rai
P.G. Department of Chemistry, Ganga Singh College, Jai Prakash University, Chapra-841 301 Bihar, India
*Corresponding Author

Published In:   Volume - 7,      Issue - 3,     Year - 2014

 View HTML        View PDF

ABSTRACT:
The rates of mercuric chloride (Lewis acid) catalysed oxidation of thioanisole and several para-substituted thioanisoles by permanganate have been studied in anhydrous acetone solutions. The kinetic rate law obtained indicates that a complex between permanganate and the Lewis acid (HgCl2) is formed before oxidation of the sulfur-containing compounds occurs. The function of the mercuric chloride is to enhance the reactivity of permanganate. A Hammett ? value of -0.60 ±0.04 is obtained for the oxidation of sulfides at 23.0 0C. A negative ? value means that the sulfur is electron deficient in the transition state. Values for the HOMO energies of sulfides and the LUMO energies for permanganate ion and the permanganate-mercuric chloride complex have been calculated. The results indicate that electron donating substituents on the ring increase the rate of the reaction and electron withdrawing groups slow down the reaction.


Keywords:

Cite this article:
K.P. Srivastava, Sanjay Kumar Rai. Kinetics and Mechanism of HgCl2 Catalysed Oxidation of Organic Sulfides by Permanganate in Non-Aqueous Medium. Asian J. Research Chem. 7(4): April 2014; Page 379-385.


Recomonded Articles:

An Investigation of nonlinear optical properties, electronic behaviour and structure-NLO relation of 1,3-Bis(3,4-dimethoxyphenyl)prop-2-en-1-one : A theoretical and computational study

Author(s): Ram Kumar, Poonam Tandon, P.S. Patil

DOI: 10.5958/0974-4150.2017.00015.3         Access: Open Access Read More

Normal Mode Analysis, Electronic Parameters and molecular docking study of 3, 5, 4’-Trihydroxy-6, 7-Dimethoxy-Flavone (Eupalitin) using First Principle

Author(s): Tanveer Hasan, Raza Murad Ghalib, Sayed Hasan Mehdi, P. K. Singh, S. S. R. Baqri

DOI: 10.5958/0974-4150.2017.00132.8         Access: Open Access Read More

Molecular Geometry, Vibrational Assignments, HOMO-LUMO, Mulliken’s charge analysis and DFT Calculations of 2-(2-Phenylaminothiazole-5-oyl)1- methyl-6-methylbenzimidazole

Author(s): S. Sangeetha, T. F. Abbs Fen Reji

DOI: 10.5958/0974-4150.2018.00149.9         Access: Open Access Read More

Kinetic Estimation of Ibuprofen and Nimesulide in Pharmaceuticals

Author(s): B.S. Virupaxappa, K.H. Shivaprasad, Raviraj M. Kulkarni, M.S. Latha

DOI:         Access: Open Access Read More

Structure-reactivity correlation in the oxidation of meta and para-substituted benzaldehydes by Tetrakis (Pyridine) Silver Dichromate

Author(s): Amol P. Kharche, Indu M. Shastri

DOI: 10.5958/0974-4150.2017.00134.1         Access: Open Access Read More

Microbial Screening of Thermally stable N-Vinyl Carbazole–co-Methoxyethyl methacrylate Copolymers: Synthesis and Characterization

Author(s): R. P. Meena, K. Abdul Wasi, K. Anver Basha

DOI: 10.5958/0974-4150.2017.00123.7         Access: Open Access Read More

Synthesis and Structure-Activity Relationship Study of Novel Isoxazole derivatives as Promising Antioxidants

Author(s): Chithra. V.S, Abbs Fen Reji. T.F, Brindha. J

DOI: 10.5958/0974-4150.2018.00014.7         Access: Open Access Read More

Spectroscopic Investigation, HOMO-LUMO and Mulliken analysis of 2-[2-(Butylamino-4-phenylaminothiazol)-5-oyl]benzothiazole by DFT study.

Author(s): B. JiniKumari, T. F. Abbs Fen Reji

DOI: 10.5958/0974-4150.2017.00137.7         Access: Open Access Read More

Preparation and Characterization of Flurbiprofen Co-crystals By Using Factorial Design

Author(s): Zalte A. G., Saudagar R. B.

DOI: 10.5958/0974-4150.2018.00034.2         Access: Open Access Read More

Spectroscopic methods (IR, EPR and Electronic) for characterization of Homobinuclear 3D complexes

Author(s): Nidhi Gupta

DOI: 10.5958/0974-4150.2017.00085.2         Access: Open Access Read More

Review on Heterogeneous Catalysis for Biodiesel Production

Author(s): Ch. V. Subbarao, K.V. Dharma Rao, T. Srinivas, Sumana V.S, Krishna Prasad K.M.M

DOI:         Access: Open Access Read More

Synthesis, Characterization and DFT studies of 2-(2-phenylaminothiazole-5-oyl)-N-methyl-6-chlorobenzimidazole

Author(s): S. Sangeetha, T.F.Abbs Fen Reji

DOI: 10.5958/0974-4150.2018.00151.7         Access: Open Access Read More

Structural and Morphological Study of Fe2O3 Nanoparticles

Author(s): S. A. Ansari, A. Azam, A.H. Naqvi

DOI:         Access: Open Access Read More

Computational Study of Corrosion Potential of Ciprofloxacin Drug: DFT Approach

Author(s): Jeetendra Bhawsar, P.K. Jain, Preeti Jain, Mukta Rani Bhawsar

DOI:         Access: Open Access Read More

Electric and Dielectric Bahaviour of PbZr0.6 Ti0.4O3 and PbSr0.6Ti0.4O3 Ceramics

Author(s): Shirish D. Kamat, Satish A. Gangavane, V.J. Fulari

DOI:         Access: Open Access Read More

Synthesis and Quantitative Structure-Antioxidant Activity Relationship Analysis of Thiazolidine-2,4-dione Analogues

Author(s): Swathi N, Subrahmanyam CVS, Satyanarayana K

DOI: 10.5958/0974-4150.2015.00005.X         Access: Open Access Read More

Kinetic and Mechanistic Study of Oxidation of Ester by KMnO4

Author(s): Sayyed Hussain, Mazhar Farooqui, M.B. Ubale

DOI:         Access: Open Access Read More

Antioxidant Properties of Gongronema latifolia

Author(s): Njoku Obioma U., Joshua Parker Elijah, Okonkwo Chukwudi C;

DOI:         Access: Open Access Read More

Antioxidant Properties of Murraya koenigii

Author(s): Njoku Obioma U., Joshua, Parker Elijah, Ossai Emmanuel C., Agu, Chidozie Victor, Ugwuanyi Juliana O.

DOI:         Access: Open Access Read More

Optimization of Cuprous Oxide Nanocrystals Deposition on Multiwalled Carbon Nanotubes

Author(s): Fasiuddin Arif Mohammad, Kishore Rapolu, Shanthan Kumar Valugonda, Srinivas Balusu

DOI:         Access: Open Access Read More

Asian Journal of Research in Chemistry (AJRC) is an international, peer-reviewed journal devoted to pure and applied chemistry..... Read more >>>

RNI: Not Available                     
DOI: 10.5958/0974-4150 

Quick Links

Latest Issues

Popular Articles


Recent Articles



Adsorption studies of p-Nitrophenol from Model aqueous solutions using Raw and Quaternised thorn melon (Cucumis metuliferus) peels
Effects of Temperature on Microstructure and Corrosion behavior of API N80 Carbon Steel
Simultaneous Spectrophotometric Estimation of Emtricitabine and Tenofovir disoproxil fumarate by Area Under Curve Method in Combined Dosage Form
Synthesis and characterization of new poly (4, 4-diaminodiphenyl sulphone)/clay modified nanocomposites
Bioaccumulation of trace elements in Cyprinus Carpio’s organs collected from Hammam Boughrara dam
Review on Discovery Studio: An important Tool for Molecular Docking
Review on Guassion, the General Purpose in Computational Chemistry for Medicinal Chemistry
Efficiency of AUTODOCK: Insilico study of Pharmaceutical Drug Molecules
Insilico Molecular docking analysis in Maestro Software
Development and Validation of a HPLC method for the Determination of Metformin hydrochloride, Nateglinide and Pioglitazone hydrochloride in Multicomponent Formulation
Determination of Tropicamide and Hydroxyamphetamine in Opthalmic formulations by RP-HPLC and its Validation
Condensation Methods for the Determination of Methoxamine Hydro Chloride in Pure and Pharmaceutical Formulations
Development and Validation of RP-HPLC Method for the Estimation of L-Methyl Folate and Tofisopam in combined Formulation
Phenolic profile, Antioxidant potential of date (Phoenix dactylifera Var. Degla Baidha and Deglet-Nour) seeds from Debila region (Oued Souf, Algeria)
Comparative Study on Chemical analysis of Thanjavur and Nagapattinam region groundwater samples
Total phenolic contents and determination of Antioxidant activity by DPPH, FRAP, and cyclic voltammetry of the fruit of Solanum nigrum (black nightshade) growing in the south of Algeria
Standardization and HPTLC Fingerprinting of Unani compound formulation Habb-e-Muqil Jadeed
Analytical Applications of Isatin in the Determination of Darunavir and Methoxamine Hydrochloride
Effect of Solvent on Kinetics of acid Catalyzed solvolysis of Amyl Methanoate Formate in water-ethylene glycol (EG) mixture
Socioeconomic valorization and development of a bio-fungicide from essential oils of four Algerian aromatic and medicinal plants: Artemisia herba alba Asso, Mentha pulegium L, Rosmarinus officinalis L and Ocimum basilicum L.

Tags


About Journal

Asian Journal of Research in Chemistry (AJRC) (ISSN: print-0974-4169, Online-0974-4150) is an international, peer-reviewed journal devoted to pure and applied chemistry. AJRC publishes Original Research Articles, Short Communications, Review Articles in all aspects of chemistry. Topics covered including the traditional areas of analytical, inorganic, organic, biochemistry, forensic, physical-theoretical chemistry as well as newer interdisciplinary areas such as agriculture, materials science, computational, medicine, spectroscopy, polymers, supramolecular, surface, chemical physics, biological, medicinal/ drugs, environmental and pharmaceutical chemistry.
The journal is published quarterly every year in last week of March, June, September and December. From January 2011, is monthly and shall be published every year in last week of Month.    
Read More  

Visitors

Today: 447
Yesterday: 631
Total: 569923