Asian Journal of Research in Chemistry

ISSN

0974-4150 (Online)
0974-4169 (Print)


Submit Article

Kinetics and Mechanism of HgCl2 Catalysed Oxidation of Organic Sulfides by Permanganate in Non-Aqueous Medium

Author(s): K.P. Srivastava, Sanjay Kumar Rai

Email(s): gscdrkpsritprin@gmail.com

DOI: Not Available

Address: K.P. Srivastava* and Sanjay Kumar Rai
P.G. Department of Chemistry, Ganga Singh College, Jai Prakash University, Chapra-841 301 Bihar, India
*Corresponding Author

Published In:   Volume - 7,      Issue - 3,     Year - 2014

 View HTML        View PDF

ABSTRACT:
The rates of mercuric chloride (Lewis acid) catalysed oxidation of thioanisole and several para-substituted thioanisoles by permanganate have been studied in anhydrous acetone solutions. The kinetic rate law obtained indicates that a complex between permanganate and the Lewis acid (HgCl2) is formed before oxidation of the sulfur-containing compounds occurs. The function of the mercuric chloride is to enhance the reactivity of permanganate. A Hammett ? value of -0.60 ±0.04 is obtained for the oxidation of sulfides at 23.0 0C. A negative ? value means that the sulfur is electron deficient in the transition state. Values for the HOMO energies of sulfides and the LUMO energies for permanganate ion and the permanganate-mercuric chloride complex have been calculated. The results indicate that electron donating substituents on the ring increase the rate of the reaction and electron withdrawing groups slow down the reaction.


Keywords:

Cite this article:
K.P. Srivastava, Sanjay Kumar Rai. Kinetics and Mechanism of HgCl2 Catalysed Oxidation of Organic Sulfides by Permanganate in Non-Aqueous Medium. Asian J. Research Chem. 7(4): April 2014; Page 379-385.


Recomonded Articles:

An Investigation of nonlinear optical properties, electronic behaviour and structure-NLO relation of 1,3-Bis(3,4-dimethoxyphenyl)prop-2-en-1-one : A theoretical and computational study

Author(s): Ram Kumar, Poonam Tandon, P.S. Patil

DOI: 10.5958/0974-4150.2017.00015.3         Access: Open Access Read More

Normal Mode Analysis, Electronic Parameters and molecular docking study of 3, 5, 4’-Trihydroxy-6, 7-Dimethoxy-Flavone (Eupalitin) using First Principle

Author(s): Tanveer Hasan, Raza Murad Ghalib, Sayed Hasan Mehdi, P. K. Singh, S. S. R. Baqri

DOI: 10.5958/0974-4150.2017.00132.8         Access: Open Access Read More

Kinetic Estimation of Ibuprofen and Nimesulide in Pharmaceuticals

Author(s): B.S. Virupaxappa, K.H. Shivaprasad, Raviraj M. Kulkarni, M.S. Latha

DOI:         Access: Open Access Read More

Structure-reactivity correlation in the oxidation of meta and para-substituted benzaldehydes by Tetrakis (Pyridine) Silver Dichromate

Author(s): Amol P. Kharche, Indu M. Shastri

DOI: 10.5958/0974-4150.2017.00134.1         Access: Open Access Read More

Molecular Geometry, Vibrational Assignments, HOMO-LUMO, Mulliken’s charge analysis and DFT Calculations of 2-(2-Phenylaminothiazole-5-oyl)1- methyl-6-methylbenzimidazole

Author(s): S. Sangeetha, T. F. Abbs Fen Reji

DOI: 10.5958/0974-4150.2018.00149.9         Access: Open Access Read More

Microbial Screening of Thermally stable N-Vinyl Carbazole–co-Methoxyethyl methacrylate Copolymers: Synthesis and Characterization

Author(s): R. P. Meena, K. Abdul Wasi, K. Anver Basha

DOI: 10.5958/0974-4150.2017.00123.7         Access: Open Access Read More

Synthesis and Structure-Activity Relationship Study of Novel Isoxazole derivatives as Promising Antioxidants

Author(s): Chithra. V.S, Abbs Fen Reji. T.F, Brindha. J

DOI: 10.5958/0974-4150.2018.00014.7         Access: Open Access Read More

Spectroscopic Investigation, HOMO-LUMO and Mulliken analysis of 2-[2-(Butylamino-4-phenylaminothiazol)-5-oyl]benzothiazole by DFT study.

Author(s): B. JiniKumari, T. F. Abbs Fen Reji

DOI: 10.5958/0974-4150.2017.00137.7         Access: Open Access Read More

Preparation and Characterization of Flurbiprofen Co-crystals By Using Factorial Design

Author(s): Zalte A. G., Saudagar R. B.

DOI: 10.5958/0974-4150.2018.00034.2         Access: Open Access Read More

Spectroscopic methods (IR, EPR and Electronic) for characterization of Homobinuclear 3D complexes

Author(s): Nidhi Gupta

DOI: 10.5958/0974-4150.2017.00085.2         Access: Open Access Read More

Review on Heterogeneous Catalysis for Biodiesel Production

Author(s): Ch. V. Subbarao, K.V. Dharma Rao, T. Srinivas, Sumana V.S, Krishna Prasad K.M.M

DOI:         Access: Open Access Read More

Synthesis, Characterization and DFT studies of 2-(2-phenylaminothiazole-5-oyl)-N-methyl-6-chlorobenzimidazole

Author(s): S. Sangeetha, T.F.Abbs Fen Reji

DOI: 10.5958/0974-4150.2018.00151.7         Access: Open Access Read More

Computational Study of Corrosion Potential of Ciprofloxacin Drug: DFT Approach

Author(s): Jeetendra Bhawsar, P.K. Jain, Preeti Jain, Mukta Rani Bhawsar

DOI:         Access: Open Access Read More

Electric and Dielectric Bahaviour of PbZr0.6 Ti0.4O3 and PbSr0.6Ti0.4O3 Ceramics

Author(s): Shirish D. Kamat, Satish A. Gangavane, V.J. Fulari

DOI:         Access: Open Access Read More

Synthesis and Quantitative Structure-Antioxidant Activity Relationship Analysis of Thiazolidine-2,4-dione Analogues

Author(s): Swathi N, Subrahmanyam CVS, Satyanarayana K

DOI: 10.5958/0974-4150.2015.00005.X         Access: Open Access Read More

Kinetic and Mechanistic Study of Oxidation of Ester by KMnO4

Author(s): Sayyed Hussain, Mazhar Farooqui, M.B. Ubale

DOI:         Access: Open Access Read More

Structural and Morphological Study of Fe2O3 Nanoparticles

Author(s): S. A. Ansari, A. Azam, A.H. Naqvi

DOI:         Access: Open Access Read More

Antioxidant Properties of Gongronema latifolia

Author(s): Njoku Obioma U., Joshua Parker Elijah, Okonkwo Chukwudi C;

DOI:         Access: Open Access Read More

Antioxidant Properties of Murraya koenigii

Author(s): Njoku Obioma U., Joshua, Parker Elijah, Ossai Emmanuel C., Agu, Chidozie Victor, Ugwuanyi Juliana O.

DOI:         Access: Open Access Read More

Reaction of Steroidal Ketones with Substituted Alkylazide

Author(s): Azhar U. Khan, M. Mushfiq, Azhar U. Khan, M. Mushfiq

DOI:         Access: Open Access Read More

Asian Journal of Research in Chemistry (AJRC) is an international, peer-reviewed journal devoted to pure and applied chemistry..... Read more >>>

RNI: Not Available                     
DOI: 10.5958/0974-4150 

Quick Links

Latest Issues

Popular Articles


Recent Articles



Preparation and Optimization of Keratin from Sheep wool using response Surface Methodology
Synthesis and Characterization of Chitosan/Carrageenan/Hydroxyethyl cellulose blended gels
Study of Solvent effect of Protic solvent on Solvolysis of Hexanoate ester and Activation parameters
Electrolyte Analysis of drinking water of Djamaa (Algeria) region and study its effect on the kidneys in Wistar rats
Distribution of Iodine in two Miscible solvents
Development of Validation of Zero order, First-order, Second-order, UV-Spectrophotometry Methods using AUC Technique for Quantitative Estimation of Linagliptin in Bulk Material and Tablets
Mercury Ions removal from Aqueous solution by Functionalized Nano-cellulose
Statistical Approach to Modelling of Activity of Phenol’s and its Derivatives against L1210 Leukaemia cells
Determination of different Physico-chemical Parameters of ground and surface water of Rajshahi and Dinajpur District of Bangladesh
Measurement, Correlation and DFT study for Solubility of Glutaric acid in Water + Ethanol binary solvents at T = (293.15 to 313.15) K
Herbal tea for the treatment of Urinary diseases as Potent diuretic and Anti-inflammatory agent
Photocatalytic Degradation of Remazol Brilliant Blue Dye in Presence of TiO2 Suspension
A Validated Simple Titrimetric Method for the Quantitative determination of Isoxsuprine hydrochloride from Pharmaceutical dosages
Phytochemical screening and Identification of Polyphenols, Evaluation of Antioxidant activity and study of Biological properties of extract Silybum marianum (L.)
Biosynthesis of Silver nanoparticles and comparing its Antifungal property with Ethanolic extract of Ixora coccinea plant
A Stability Indicating Method for estimating Emtricitabine and Tenofovir disoproxil fumarate simultaneously in Bulk and Combined dosage form by RP-HPLC
Synthesis and Characterization of Novel Ag(I)-18C6/DB18C6 Complexes
Synthesis, Characterization and Antibacterial Activity of O-Alkyl/O-Aryl trithiophosphate derivatives of Niobium (V)
Antibacterial Screening of Clerodendrum infortunatum leaves: Experimental and Molecular docking studies
Development, Validation and Application on Seized materials by UV Spectrophotometric Method for the determination of a Solid Semi-legal Drug: Tramadol Hydrochloride Case

Tags


About Journal

Asian Journal of Research in Chemistry (AJRC) (ISSN: print-0974-4169, Online-0974-4150) is an international, peer-reviewed journal devoted to pure and applied chemistry. AJRC publishes Original Research Articles, Short Communications, Review Articles in all aspects of chemistry. Topics covered including the traditional areas of analytical, inorganic, organic, biochemistry, forensic, physical-theoretical chemistry as well as newer interdisciplinary areas such as agriculture, materials science, computational, medicine, spectroscopy, polymers, supramolecular, surface, chemical physics, biological, medicinal/ drugs, environmental and pharmaceutical chemistry.
The journal is published quarterly every year in last week of March, June, September and December. From January 2011, is monthly and shall be published every year in last week of Month.    
Read More  

Visitors

Today: 318
Yesterday: 374
Total: 419469