ISSN

0974-4150 (Online)
0974-4169 (Print)


Author(s): Suman Bhatti, Alok Chaturvedi

Email(s): alok_chat.ajm@rediffmail.com

DOI: 10.5958/0974-4150.2020.00025.5   

Address: Suman Bhatti2, Alok Chaturvedi2 1Department of Chemistry, Pt. N.R.S. Govt. College, Rohtak, Haryana 2Synthetic and Surface Science Laboratory, Department of Chemistry, S. P. C. Govt. College, Ajmer 305001, Rajasthan, India *Corresponding Author

Published In:   Volume - 13,      Issue - 2,     Year - 2020


ABSTRACT:
Monochloro-niobium(V) bis-O-alkyl/O-aryl trithiophosphates, ClNb[ROP(S)SS]2 (where R = Me, Et, Pri, Bui, Ph, CH3-Ph) have been synthesized by the reaction of niobium pentachloride with O-alkyl /O-aryl trithiophosphoric acid in 1:2 molar ratio, in refluxing ethanol. O-alkyl/O-aryl trithiophosphate derivatives of niobium (V) are pale yellow monomeric solids, soluble in co-ordinating solvents like DMSO, DMF and exhibit high sensitivity towards moisture. The newly synthesized derivatives have been characterized by elemental analysis, molecular weight measurement and spectroscopic (IR, 1H and 31P NMR) studies. On the basis of it is postulated that niobium is in penta-co-ordinated state and new derivatives show trigonal bipyramidal geometry. Two O-alkyl /O-aryl trithiophosphoric acid ligands are co-ordinated to niobium ion as a bidentate ligand chelating via two thiolate S atoms. Each of them forms a four-membered chelate ring.


Cite this article:
Suman Bhatti, Alok Chaturvedi. Synthesis, Characterization and Antibacterial Activity of O-Alkyl/O-Aryl trithiophosphate derivatives of Niobium (V). Asian J. Research Chem. 2020; 13(2):123-127. doi: 10.5958/0974-4150.2020.00025.5


Recomonded Articles:

Author(s): Virupakshi Prabhakar, Kondra Sudhakar Babu, L.K. Ravindranath, M. Sahanoor Basha, J. Latha

DOI: 10.5958/0974-4150.2017.00012.8         Access: Open Access Read More

Author(s): Pankaj Baboo, Girendra Gautam, S.K. Gupta

DOI: 10.5958/0974-4150.2017.00039.6         Access: Open Access Read More

Author(s): Maqdoom Farooqui, Syed Nazimuddin

DOI: 10.5958/0974-4150.2017.00026.8         Access: Open Access Read More

Author(s): KP Bhusari, ND Amnerkar, PB Khedekar, MK Kale, RP Bhole

DOI:         Access: Open Access Read More

Author(s): S.B. Junne, Archana B. Kadam, Archana Y. Vibhute, S.L. Shinde, R.B. Patil, Y.B. Vibhute

DOI:         Access: Open Access Read More

Author(s): Sindhu. T. J, Akhilesh K. J, Anju. Jose, Binsiya K. P, Blessy Thomas, Elizabeth Wilson

DOI: 10.5958/0974-4150.2020.00026.7         Access: Closed Access Read More

Author(s): Bhaskar VH, Kumar M, Balakrishnan BR, Sangameswaran B

DOI:         Access: Open Access Read More

Author(s): Vijaya B Reddy, Rajeev K, Singla Varadaraj Bhat G, Gautham G Shenoy

DOI:         Access: Open Access Read More

Author(s): Swapna S Kulkarni, AP Mehere, Priyank A Shenoy

DOI:         Access: Open Access Read More

Author(s): T.V. Yuvaraj, S. Hurmath Unnissa, N.S.Surendiran, M. Azeez Ur rahman, V.Binumon

DOI:         Access: Open Access Read More

Author(s): Madhu Yadav, Pankaj Baboo, Nisha Gupta, Vandana Arora

DOI: 10.5958/0974-4150.2018.00143.8         Access: Open Access Read More

Author(s): Etusim, P.E., Okafor, E.E, Nwachukwu, N.C, Melariri, P.E.,Ogbonnaya C.I

DOI:         Access: Open Access Read More

Author(s): NS Mahajan, RL Jadhav, KK Mali, NV Pimpodkar, AM Manikrao

DOI:         Access: Open Access Read More

Asian Journal of Research in Chemistry (AJRC) is an international, peer-reviewed journal devoted to pure and applied chemistry..... Read more >>>

RNI: Not Available                     
DOI: 10.5958/0974-4150 

Popular Articles


Recent Articles




Tags