ISSN

0974-4150 (Online)
0974-4169 (Print)


Author(s): Surabhi Sagar, Arshi Rastogi

Email(s): arshirastogi@gmail.com

DOI: 10.52711/0974-4150.2022.00057   

Address: Surabhi Sagar1, Arshi Rastogi2*
1Assistant Professor, BFIT Group of Institutions, Dehradun, Uttarakhand.
2Associate Professor, KLDAV PG College, Roorkee, Distt. Haridwar, Uttarakhand.
*Corresponding Author

Published In:   Volume - 15,      Issue - 5,     Year - 2022


ABSTRACT:
In the present study a Charophyta green alga Chara sp. has been proven to be a very effective and promising adsorbing biomass for the removal of an acidic dye, Methyl Orange [MO] from synthetic wastewater. Adsorption efficiency of alga was studied as a function of various operative variables, such as the contact time to reach equilibrium, pH of an aqueous solution, adsorbent dosage, and temperature for dye removal. The experimental data were analyzed by Langmuir, Freundlich, Temkin, and Dubinin-Radushkevich (D-R) models of adsorption isotherms, and best fit results were found for the Langmuir isotherm model, based on its correlation coefficient values. Pseudo-first-order and Pseudo-second-order kinetic models were applied to describe the adsorption process. It was found that the adsorption of methyl orange could be best described by the pseudo-second-order model. Values of Gibbs free energy (?G), entropy ((?S), and enthalpy change (?H) indicated the spontaneity, randomness, and endothermic nature of the reaction. FTIR studies showed the involvement of carboxyl, hydroxyl, and amide groups in the adsorption process. SEM micrographs displayed the morphological changes on the adsorbent surface, and BET analysis determined the surface area. To check the adsorbent reusability, repeated adsorption-desorption experiments were carried out for five consecutive cycles. The result shows that Chara sp. could be an effectual and reasonable adsorbent material for the management of MO-bearing wastewater.


Cite this article:
Surabhi Sagar, Arshi Rastogi. Adsorption Performance and Reuse Potential of a Green Alga for the removal of an Acidic dye from Synthetic Wastewater. Asian Journal of Research in Chemistry. 2022; 15(5):319-6. doi: 10.52711/0974-4150.2022.00057

Cite(Electronic):
Surabhi Sagar, Arshi Rastogi. Adsorption Performance and Reuse Potential of a Green Alga for the removal of an Acidic dye from Synthetic Wastewater. Asian Journal of Research in Chemistry. 2022; 15(5):319-6. doi: 10.52711/0974-4150.2022.00057   Available on: https://ajrconline.org/AbstractView.aspx?PID=2022-15-5-3


REFERENCES:
1.    Salleh MAM, Mahmoud DK, Karim WAWA Idris A. Cationic and anionic dye adsorption by agricultural solid wastes. A comprehensive review. Desalination 2011; 280: 1–13.
2.    Sahare AB, Gharde BD. Adsorption studies of Co (II) from aqueous solution using Mangifera indica bark substrate. Asian J. Research Chem. 2017; 10(3): 259 – 263.  
3.    Saini. R D. Synthetic Textile Dyes: Constitution, dying process and environmental impacts, Asian J. Research Chem. 2018; 11(1): 206-214.
4.    Sagar S, Rastogi A. Biosorption of Methylene blue from aqueous solutions by blue-green algae Oscillatoria sp.: Kinetic and equilibrium studies, J. Applicable Chem., 2017; 6(3), 374-384
5.    Mohindru J.J, Garg U. K, Gupta R. Coagulation-Flocculation technologies for arsenic removal -A review. Asian J. Research Chem. 2017; 10(3): 405 – 413.
6.    Prabhakaran, R.M.Niranjan, V. Sreenivasan V.M. Kumar S.T. Decolorization of Synthetic Dye by Photocatalytic Oxidation. Asian J. Research Chem. 2009; 2(3) : 250-252.
7.    Yadav, S. Tyagi, D.K., Yadav, O.P. An overview of effluent treatment for the removal of pollutant dyes. Asian J. Research Chem. 2012; 5(1) : 1-7.
8.    Mitrogiannis D., Markou, G. Celekli A., Bozkurt, H. Biosorption of methylene blue on Arthrospira platensis biomass: Kinetic, equilibrium and thermodynamic studies. J Environmental Chemical Engineering, 2015; 3: 670-680.
9.    Adinew, B. Kebede, T.,Shimelis, B. Removal of Congo Red and Methyl violet Dyes from wastewater by Adsorption on low-cost Material. Asian J. Research Chem. 2011; 4(7) :1148-1157
10.    Rai, M. Hussain, S. Pathan, M.A.A. Farooqui. M. Adsorption Studies of Crystal Violet on Sand. Asian J. Research Chem. 2011; 4(6): 890-892.
11.    Nandkishore, T., Vidyadhar S.. Adsorption of zinc onto microwave-assisted carbonized Acacia nilotica bark. Asian J. Research Chem. 2017; 10(1): 45- 53.
12.    Sharma, N., Alam, T., Rastogi, A., Tarannum, H.,Saini,.G. Adsorptive removal of Alizarine red-s from aqueous solutions by using Cobalt and Copper Ferricynides, J. Applicable Chem. 2015; 4(3): 871-882.
13.    Velkova, Z. Kirova, G. Gochev, V. Kafadarova V., Stoytcheva, M., Biosorption of methyl orange by waste biomass of Streptomyces fradiae, Scientific works of the University of Food Technologies, 2014; LXI, 546-550.
14.    Chen, H. Zhao, Wu J. J., Dai, G., Isotherm, thermodynamic, kinetics and adsorption mechanism studies of methyl orange by surfactant modified silkworm exuviae. J. hazard. materials, 2011; 192(1): 246-254.
15.    Subbaiahm M. V., Kim, D. S. Adsorption of methyl orange from aqueous solution by aminated pumpkin seed powder: Kinetics, isotherms, and thermodynamic studies. Ecotoxicology and environmental safety, 2016; 128: 109-117.
16.    Chen, S. Zhang, J. Zhang, C. Yue, Q. Li Y. Li, C., Equilibrium and kinetic studies of methyl orange and methyl violet adsorption on activated carbon derived from Phragmites australis. Desalination, 2010; 252(1-3): 149-156.
17.    Sagar S., Rastogi A. Adsorptive Elimination of an Acidic Dye from Synthetic Wastewater using Yellow Green Algae along with Equilibrium Data Modelling. Asian J. Research Chem. 2018; 11(5): 778-786.
18.    Sagar, S. Rastogi, A. A comparative investigation on the biosorption performance of non-viable Vaucheria sp. and Chara sp. for a hazardous basic dye-Methylene blue, J. Applicable Chem., 2019; 8(1): 335-350.
19.    Brunauer, S. Emmett P. H. Teller, E. Adsorption of gases in multimolecular layers, Journal of the American chemical society, 1938; 60(2): 309-319.
20.    Langmuir, I. The adsorption of gases on plane surfaces of glass, mica and platinum. Journal of the American Chemical Society, 1918; 40(9): 1361-1403.
21.    HMF, F. Over the adsorption in solution. Z Phys. Chem., 1906; 57: 385-471.
22.    Temkin M. J. Pyzhev, V. Recent modifications to Langmuir isotherms, Acta Physiochim. URSS 1940; 12: 217- 225.
23.    Dubinin, M. The potential theory of adsorption of gases and vapors for adsorbents with energetically nonuniform surfaces. Chemical Reviews, 1960; 60(2): 235-241.
24.    Celekli, A. Tanrivedi, B. Bozkurt, H. Predictive Modelling of removal of Lanaset Red G on Chara contraria; kinetic, equilibrium, and thermodynamic studies, Chem. Eng. J , 2011; 169: 166-172.
25.    Smaranda, C. Bulgariu D. Gavrilescu, M. An investigation of the sorption of Acid Orange 7 from aqueous solution onto the soil. Environmental Engineering and Management Journal, 2009; 8(6): 1391-1402.
26.    Mall, I. D.. Srivastava V. C. Agarwal, N. K. Removal of Orange-G and Methyl Violet dyes by adsorption onto bagasse fly ash—kinetic study and equilibrium isotherm analyses. Dyes and pigments, 2006; 69(3): 210-223.
27.    Özer, A. Akkaya G. Turabik, M. Biosorption of acid blue 290 (AB 290) and acid blue 324 (AB 324) dyes on Spirogyra rhizopus. J. Hazard. Materials, 2006; 135(1-3): 355-364.
28.    Mittal, A. Malviya, A. Kaur, D. Mittal J. Kurup, L. Studies on the adsorption kinetics and isotherms for the removal and recovery of Methyl Orange from wastewaters using waste materials. J. Hazard. Materials, 2007;148(1-2): 229-240.
29.    Celekli, A. İlgün G. Bozkurt, H. Sorption equilibrium, kinetic, thermodynamic, and desorption studies of Reactive Red 120 on Chara contraria. Chemical Engineering Journal, 2012; 191: 228-235.
30.    Patel, H. Vashi R. T. Champaneri, V. A. Continuous Adsorption of Methylene Blue Dye from Aqueous Solution onto Guava Leaf Powder in Fixed Bed, J. Applicable Chem. 2019; 8 (5): 2246-2254.
31.    Dubey, S.S. Rao, B.S. Kinetic Models in Adsorption - A Review, Asian J. Research Chem. 2012; 5(1): 8-13.
32.    Lagergren, S. Zur theorie der sogenannten adsorption geloster stoffe. Kungliga svenska vetenskapsakademiens. Handlingar, 1898; 24: 1-39.
33.    Ho Y. S. McKay, G. Pseudo-second order model for sorption processes. Process biochemistry, 1999; 34(5): 451-465.
34.    Nemr, A. El. Abdelwahab, O. Khaled A. Z. Z. A. Sikaily, A. El. Removal of chrysophenine dye (DY-12) from aqueous solution using dried Ulva lactuca. Egyptian Journal of Aquatic Research, 2005; 31: 86-98
35.    Stirk W. A. Van Staden, J. Desorption of cadmium and the reuse of brown seaweed-derived products as biosorbents. Botanica Marina, 2002; 45(1): 9-16.
36.    Hu J. Shipley, H. J. Regeneration of spent TiO 2 nanoparticles for Pb (II), Cu (II), and Zn (II) removal. Environmental Science and Pollution Research, 2013; 20(8): 5125-5137.

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