Asian Journal of Research in Chemistry

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0974-4150 (Online)
0974-4169 (Print)


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Solvent effect and Activation Parameters: A Kinetic Reaction of Ethyl Caprylate in Water-Acetone Media

Author(s): A.K. Singh

Email(s): dr.anilkumarsingh2009@gmail.com

DOI: 10.52711/0974-4150.2021.00076   

Address: A.K. Singh
Teerthanker Mahaveer University, Moradabad, India.
*Corresponding Author

Published In:   Volume - 14,      Issue - 6,     Year - 2021

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ABSTRACT:
The kinetic result of hydrolysis of Ethyl Caprlyate has been investigated at different composition of aqueous-organic solvent with Acetone (30-70% v/v) over the temperature range of 20 to 400c. The calculated result follows second order kinetics and is observed that the rate decreases with increasing proportion of Acetone. This behavior is attributed electrostatic nature that various solvent-solute interaction in reaction media. Linear plots of Logk against water concentration shows that equilibrium shifted from dense form to bulky form. Iso-kinetic temperature has been determined with the help of slopes of (?H*) versus (?S*). Thermodynamic parameter has been calculated with the help of Wynne-Jones and Eyring equation.


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Cite this article:
A.K. Singh. Solvent effect and Activation Parameters: A Kinetic Reaction of Ethyl Caprylate in Water-Acetone Media. Asian Journal of Research in Chemistry. 2021; 14(6):441-4. doi: 10.52711/0974-4150.2021.00076

Cite(Electronic):
A.K. Singh. Solvent effect and Activation Parameters: A Kinetic Reaction of Ethyl Caprylate in Water-Acetone Media. Asian Journal of Research in Chemistry. 2021; 14(6):441-4. doi: 10.52711/0974-4150.2021.00076   Available on: https://ajrconline.org/AbstractView.aspx?PID=2021-14-6-9


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Asian Journal of Research in Chemistry (AJRC) (ISSN: print-0974-4169, Online-0974-4150) is an international, peer-reviewed journal devoted to pure and applied chemistry. AJRC publishes Original Research Articles, Short Communications, Review Articles in all aspects of chemistry. Topics covered including the traditional areas of analytical, inorganic, organic, biochemistry, forensic, physical-theoretical chemistry as well as newer interdisciplinary areas such as agriculture, materials science, computational, medicine, spectroscopy, polymers, supramolecular, surface, chemical physics, biological, medicinal/ drugs, environmental and pharmaceutical chemistry.
The journal is published quarterly every year in last week of March, June, September and December. From January 2011, is monthly and shall be published every year in last week of Month.    
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